Ecotoxicity studies reveal that organic cations in dicamba-derived ionic liquids can pose a greater environmental risk than the herbicide itself

J Homa, W Stachowiak, A Olejniczak… - Science of The Total …, 2024 - Elsevier
The following research provides novel and relevant insights into potential environmental
consequences of combination of various organic cations with commercial systemic herbicide …

Dicamba-based herbicides: herbicidal ionic liquids versus commercial forms

J Pernak, DK Kaczmarek, T Rzemieniecki… - Journal of agricultural …, 2020 - ACS Publications
Dicamba is a widely applied herbicide for crop protection and has potential for volatility. New
formulations containing dicamba with greatly reduced volatility, introduced to the market in …

Double-action herbicidal ionic liquids based on dicamba esterquats with 4-CPA, 2, 4-D, MCPA, MCPP, and clopyralid anions

A Syguda, M Wojcieszak, K Materna… - ACS Sustainable …, 2020 - ACS Publications
Herbicides such as (3, 6-dichloro-2-methoxy) benzoic acid (dicamba),(4-chloro-2-
methylphenoxy) acetic acid (MCPA),(2, 4-dichlorophenoxy) acetic acid (2, 4-D), or (±)-2-(4 …

Toxicity evaluation of selected ammonium-based ionic liquid forms with MCPP and dicamba moieties on Pseudomonas putida

A Piotrowska, A Syguda, B Wyrwas, Ł Chrzanowski… - Chemosphere, 2017 - Elsevier
Combination of the hydrophilic herbicidal anion with hydrophobic, antimicrobial ammonium
cation allows to obtain compounds in ionic liquid form with better properties then …

Effect of cation hydrophobicity in dicamba-based ionic liquids on herbicide accumulation and bioavailability in soil

N Lisiecka, A Parus, V Verkhovetska… - Journal of …, 2023 - Elsevier
One of the main environmental problems due to using herbicides in agriculture is their
mobility and leachability from crop fields. Using an 'ionic liquid'strategy, we set out to see if it …

Confusing ions on purpose: how many parent acid molecules can be incorporated in a herbicidal ionic liquid?

JL Shamshina, HB Wineinger… - ACS Sustainable …, 2021 - ACS Publications
To expand the application range of herbicidal ionic liquids (HILs), we attempted to increase
the amount of the systemic herbicide dicamba in its HILs through the formation of neither …

Two herbicides in a single compound: double salt herbicidal ionic liquids exemplified with glyphosate, dicamba, and MCPA

H Choudhary, J Pernak, JL Shamshina… - ACS Sustainable …, 2017 - ACS Publications
Herbicidal ionic liquids (HILs) have been demonstrated to have potential as highly effective
herbicides that may also have different modes of action that their neutral precursors. Here …

Herbicidal ionic liquids: A promising future for old herbicides? Review on synthesis, toxicity, biodegradation, and efficacy studies

W Wilms, M Woźniak-Karczewska… - Journal of agricultural …, 2020 - ACS Publications
The transformation of agrochemicals into herbicidal ionic liquids (HILs) has been suggested
as a solution to problems associated with commercial forms of herbicides. The aim of this …

Ionic liquid forms of the herbicide dicamba with increased efficacy and reduced volatility

OA Cojocaru, JL Shamshina, G Gurau, A Syguda… - Green …, 2013 - pubs.rsc.org
Twenty eight new dicamba (3, 6-dichloro-2-methoxybenzoic acid)-based herbicidal salts,
have been synthesized and characterized in order to attempt to improve the efficacy of this …

The influence of anion species on the toxicity of 1-alkyl-3-methylimidazolium ionic liquids observed in an (eco) toxicological test battery

M Matzke, S Stolte, K Thiele, T Juffernholz, J Arning… - Green …, 2007 - pubs.rsc.org
To enlarge the restricted knowledge about the hazard potentials of ionic liquids to man and
the environment we have concentrated on analysing systematically the anion effect of six …