Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Cyclopentadienyl ligands in lanthanide single-molecule magnets: one ring to rule them all?

BM Day, FS Guo, RA Layfield - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The discovery of materials capable of storing magnetic information at the level
of single molecules and even single atoms has fueled renewed interest in the slow magnetic …

Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets

F Liu, L Spree, DS Krylov, G Velkos… - Accounts of chemical …, 2019 - ACS Publications
Conspectus A characteristic phenomenon of lanthanide–fullerene interactions is the transfer
of metal valence electrons to the carbon cage. With early lanthanides such as La, a …

An organolanthanide building block approach to single-molecule magnets

KLM Harriman, M Murugesu - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) are highly sought after for their potential
application in high-density information storage, spintronics, and quantum computing. SMMs …

Blocking like it's hot: a synthetic chemists' path to high-temperature lanthanide single molecule magnets

CAP Goodwin - Dalton Transactions, 2020 - pubs.rsc.org
Progress in the synthesis, design, and characterisation of single-molecule magnets (SMMs)
has expanded dramatically from curiosity driven beginnings to molecules that retain …

Recent Developments in Lanthanide Single‐Molecule Magnets

J Lu, M Guo, J Tang - Chemistry–An Asian Journal, 2017 - Wiley Online Library
Single‐molecule magnets (SMMs) exhibiting slow relaxation of magnetization of purely
molecular origin are highly attractive owing to their potential applications in spintronic …

Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal–metal bond

F Liu, G Velkos, DS Krylov, L Spree, M Zalibera… - Nature …, 2019 - nature.com
Engineering intramolecular exchange interactions between magnetic metal atoms is a
ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature …

[图书][B] Lanthanide single molecule magnets

J Tang, P Zhang - 2015 - Springer
Magnetic materials play an important role in our modern civilization and have driven great
advances in the field of information technology. However, the storage densities are still …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

High-temperature magnetic blocking in a monometallic dysprosium azafullerene single-molecule magnet

Z Hu, Y Wang, A Ullah, GM Gutiérrez-Finol… - Chem, 2023 - cell.com
Single-molecule magnets (SMMs) showing magnetic blocking near or above liquid nitrogen
temperature have recently been achieved by inducing exceptionally strong and axial crystal …