We report here a novel family of boraolympicenes, structurally featuring boron-doping at the
concave 11a-position of their π-skeletons and synthetically prepared via a facile one-pot …

Neutral 1-boraphenalene displays the isoelectronic structure of the phenalenyl carbocation
and is expected to behave as an attractive organoboron multi-redox system. However, the …

π-Conjugated macrocycles involving electron-deficient boron species have received
increasing attention due to their intriguing tunable optoelectronic properties. However, most …

A highly bent triarylborane, 9‐boratriptycene, was generated in solution by selective
protodeboronation of the corresponding tetra‐aryl boron ate complex with the strong …

Conspectus Boron heterocycles represent an important subset of heteroatom-incorporated
rings, attracting attention from organic, inorganic, and materials chemists. The empty pz …

The alumole Cp3tAlC4Et4 (Cp3t= 1, 2, 4-tris (tert-butyl) cyclopentadienyl) is reported to be
capable of transferring its butadiene moiety to aryl (dihalo) boranes to generate boroles …

We present the first examples of alkylated derivatives of the macropolyhedral boron hydride,
anti-B18H22, which is the gain medium in the first borane laser. This new series of ten highly …

Direct functionalization and Pd-catalyzed cross-coupling of difuryl (supermesityl) borane (1)
led to highly emissive organoborane compounds 3 and 4. Photophysical and TD-DFT …

Abstract Molecular ribbons (MRs), one‐dimentional topological polycyclic aromatic
hydrocarbons (PAHs), are of importance for synthetic chemistry and material sciences …

We introduce a new boron‐doped cyclophane, the hexabora [16] cyclophane B6‐FMes, in
which six tricoordinate borane moieties alternate with short conjugated p‐phenylene linkers …