One-dimensional reactivity in catalysis studied with the scanning tunnelling microscope

FM Leibsle, PW Murray, SM Francis, G Thornton… - Nature, 1993 - nature.com
THE scanning tunnelling microscope (STM) has yielded great insight into the structure of
surfaces and into the dynamics of surface reconstruction and adsorption1. We show here …

Atomic and macroscopic reaction rates of a surface-catalyzed reaction

J Wintterlin, S Volkening, TVW Janssens, T Zambelli… - Science, 1997 - science.org
The catalytic oxidation of carbon monoxide (CO) on a platinum (111) surface was studied by
scanning tunneling microscopy. The adsorbed oxygen atoms and CO molecules were …

Molecular manipulation using a tunnelling microscope

JS Foster, JE Frommer, PC Arnett - Nature, 1988 - nature.com
In a very short time the scanning tunnelling microscope has become an important tool in
surface science, and physics in general1–3. Its primary use has been to obtain atomic …

Contrast mechanism for resolving organic molecules with tunnelling microscopy

JK Spong, HA Mizes, LJ LaComb Jr, MM Dovek… - Nature, 1989 - nature.com
THE scanning tunnelling microscope (STM) is now an established tool for the study of
ordered metal and semiconductor surfaces on an atomic scale1, 2. Here we demonstrate the …

Complex pathways in dissociative adsorption of oxygen on platinum

T Zambelli, JV Barth, J Wintterlin, G Ertl - Nature, 1997 - nature.com
Gas adsorption on solid surfaces is the basis of heterogeneous catalysis. Gas–surface
interactions may be complex and in many cases the fundamental mechanisms of the …

Positioning single atoms with a scanning tunnelling microscope

DM Eigler, EK Schweizer - Nature, 1990 - nature.com
SINCE its invention in the early 1980s by Binnig and Rohrer1, 2, the scanning tunnelling
microscope (STM) has provided images of surfaces and adsorbed atoms and molecules …

Nanometre-scale chemical modification using a scanning tunnelling microscope

Y Utsugi - Nature, 1990 - nature.com
THE potential of the scanning tunnelling microscope (STM) as a tool for the high-resolution
manipulation of surfaces and surface-adsorbed phases has been amply demonstrated1–5 …

Direct instrumental identification of catalytically active surface sites

JHK Pfisterer, Y Liang, O Schneider, AS Bandarenka - Nature, 2017 - nature.com
The activity of heterogeneous catalysts—which are involved in some 80 per cent of
processes in the chemical and energy industries—is determined by the electronic structure …

Velocity-resolved kinetics of site-specific carbon monoxide oxidation on platinum surfaces

J Neugebohren, D Borodin, HW Hahn, J Altschäffel… - Nature, 2018 - nature.com
Catalysts are widely used to increase reaction rates. They function by stabilizing the
transition state of the reaction at their active site, where the atomic arrangement ensures …

Imaging of spatio-temporal pattern evolution during carbon monoxide oxidation on platinum

HH Rotermund, W Engel, M Kordesch, G Ertl - Nature, 1990 - nature.com
THE rates of chemical reactions may exhibit temporal oscillations, even when the reaction
parameters are kept constant. These oscillations might be associated with spatial pattern …