Mechanisms of nucleation and stationary states of electrochemically generated nanobubbles

YA Perez Sirkin, ED Gadea, DA Scherlis… - Journal of the …, 2019 - ACS Publications
Gas evolving reactions are ubiquitous in the operation of electrochemical devices. Recent
studies of individual gas bubbles on nanoelectrodes have resulted in unprecedented control …

Electrochemistry of single nanobubbles. Estimating the critical size of bubble-forming nuclei for gas-evolving electrode reactions

SR German, MA Edwards, Q Chen, Y Liu, L Luo… - Faraday …, 2016 - pubs.rsc.org
In this article, we address the fundamental question:“What is the critical size of a single
cluster of gas molecules that grows and becomes a stable (or continuously growing) gas …

The behavior of surface nanobubbles on different substrates in electrochemistry

T Nie, Q Xu, Y She, X Ye, M Wang, X Luo… - Journal of Molecular …, 2024 - Elsevier
In the gas evolution reaction, surface nanobubbles generally nucleate heterogeneously and
grow on the electrode. It is important to understand the relationship between the evolution of …

Single-entity electrochemistry of nano-and microbubbles in electrolytic gas evolution

Q Chen, J Zhao, X Deng, Y Shan… - The Journal of Physical …, 2022 - ACS Publications
Gas bubbles are found in diverse electrochemical processes, ranging from electrolytic water
splitting to chlor-alkali electrolysis, as well as photoelectrochemical processes …

Voltammetric Determination of the Stochastic Formation Rate and Geometry of Individual H2, N2, and O2 Bubble Nuclei

MA Edwards, HS White, H Ren - ACS nano, 2019 - ACS Publications
Herein, we report a general voltammetric method to characterize the electrochemical
nucleation rate and nuclei of single nanobubbles. Bubble nucleation is indicated by a sharp …

Influence of bubbles on the energy conversion efficiency of electrochemical reactors

A Angulo, P van der Linde, H Gardeniers, M Modestino… - Joule, 2020 - cell.com
Bubbles are known to influence energy and mass transfer in gas-evolving electrodes.
However, we lack a detailed understanding on the intricate dependencies between bubble …

Revisited electrochemical gas evolution reactions from the perspective of gas bubbles

W Yin, Y Cai, L Xie, H Huang, E Zhu, J Pan, J Bu… - Nano Research, 2023 - Springer
Electrochemical gas evolution reactions are common but essential in many electrochemical
processes including water electrolysis. During these processes, gas bubbles are constantly …

Electrochemical Nucleation of Stable N2 Nanobubbles at Pt Nanoelectrodes

Q Chen, HS Wiedenroth, SR German… - Journal of the American …, 2015 - ACS Publications
Exploring the nucleation of gas bubbles at interfaces is of fundamental interest. Herein, we
report the nucleation of individual N2 nanobubbles at Pt nanodisk electrodes (6–90 nm) via …

Nucleation of surface nanobubbles in electrochemistry: Analysis with nucleation theorem

Y Ma, M Huang, G Mutschke, X Zhang - Journal of Colloid and Interface …, 2024 - Elsevier
The formation of single bubbles at nanoelectrodes during electrochemical reactions allows
to accurately identify the critical nucleus for bubble formation. As demonstrated before …

Gas bubbles in electrochemical gas evolution reactions

X Zhao, H Ren, L Luo - Langmuir, 2019 - ACS Publications
Electrochemical gas evolution reactions are of vital importance in numerous electrochemical
processes including water splitting, chloralkaline process, and fuel cells. During gas …