Interfacial Electron Modulation to Boost Driving Force: Partial Sulfurization over Co-MOF@Fe2O3 p–n Heterojunctions for Water Splitting

CL Peng, LY Zhang, N Zhang, J Guo… - ACS Materials …, 2024 - ACS Publications
Herein, ap–n junction composed of cobalt-based metal–organic frameworks (Co-MOFs) and
Fe2O3 has been designed to provide a strong built-in electric field (B-IEF) to enhance …

Engineering metal-organic framework nanosheets with electronically modulated in-plane heterojunctions for robust high-current-density water splitting

S Zhao, L Deng, Y Xiong, F Hu, L Yin, D Yu, LL Li… - Science China …, 2023 - Springer
To simultaneously achieve low overpotentials and stable operation for water splitting at high
current densities, bifunctional electrocatalysts must be designed based on interfacial …

Heterostructure of Semiconductors on Self-Supported Cuprous Phosphide Nanowires for Enhanced Overall Water Splitting

X Xu, Y He, W Huang, A Cao, L Kang… - ACS Applied Materials & …, 2022 - ACS Publications
Rational design, controllable synthesis, and an in-depth mechanism study of Cu-based
bifunctional semiconductor heterostructures toward overall water splitting (OWS) are …

Operando-reconstructed polyatomic ion layers boost the activity and stability of industrial current-density water splitting

Y Zhao, Y Wu, Q Wen, D Huang, R Yang, H Wang… - Science Bulletin, 2024 - Elsevier
Metal–organic frameworks have garnered attention as highly efficient pre-electrocatalysts for
the oxygen evolution reaction (OER). Current structure–activity relationships primarily rely …

Interface Engineering of Ni3Fe and FeV2O4 Coupling with Carbon-Coated Mesoporous Nanosheets for Boosting Overall Water Splitting at 1500 mA cm–2

H Zhang, G Qian, T Yu, J Chen, L Luo… - … Sustainable Chemistry & …, 2021 - ACS Publications
Constructing a heterojunction is vital to increase the performance of non-noble metal
catalysts for overall water splitting (OWS) at large current density. Herein, we synthesize a …

A corrosion-engineered transition metal multi-anionic interface for efficient electrocatalysis toward overall water splitting

Q Guo, X Liu, C Ke, W Xiao, X Yang - New Journal of Chemistry, 2023 - pubs.rsc.org
Rational design and controllable synthesis of transition metal multi-anionic structures to
cooperatively catalyze the hydrogen evolution reaction (HER) and the oxygen evolution …

NiFe-Based Semi-MOF Embedded by Sulfide Particles Reconstructed a Three-Layer Sandwich Structure for Alkaline Overall Water Splitting

S Yu, N Zhang, J Li, J Yin, Y Wang, Z Wu… - ACS Sustainable …, 2024 - ACS Publications
A metal–organic framework (MOF) embedded by transition metal sulfide (TMS) particles is
one of the promising electrocatalyst candidates for overall water splitting (OWS) due to the …

Interface engineering on amorphous/crystalline hydroxides/sulfides heterostructure nanoarrays for enhanced solar water splitting

H Zhang, Y Zhou, M Xu, A Chen, Z Ni, O Akdim… - ACS …, 2022 - ACS Publications
Developing highly efficient and stable noble-metal-free electrocatalysts for water splitting is
critical for producing clean and sustainable energy. Here, we design a hierarchical transition …

Vacancy engineering and hydrophilic construction of CoFe-MOF for boosting water splitting by in situ phytic acid treatment

T Zhao, D Zhong, G Hao, Q Zhao - Applied Surface Science, 2023 - Elsevier
Deliberate engineering of the structures and components of Metal–organic frameworks
(MOFs) can provide unlimited potential for developing efficient electrocatalysts for water …

Interfacial engineering of heterostructured Fe-Ni 3 S 2/Ni (OH) 2 nanosheets with tailored d-band center for enhanced oxygen evolution catalysis

G Li, Z Ma, W Li, Y Nie, L Pei, J Zhong, Q Miao… - Dalton …, 2022 - pubs.rsc.org
Hydrogen production by electrochemical water splitting suffers from high kinetic barriers in
the anodic oxygen evolution reaction (OER), which limits the overall efficiency. Herein, we …