Hydrogen‐Binding‐Initiated Activation of O− H Bonds on a Nitrogen‐Doped Surface for the Catalytic Oxidation of Biomass Hydroxyl Compounds

X Liu, Y Luo, H Ma, S Zhang, P Che… - Angewandte …, 2021 - Wiley Online Library
Hydrogen binding of molecules on solid surfaces is an attractive interaction that can be used
as the driving force for bond activation, material‐directed assembly, protein protection, etc …

Hydrogen bonding-assisted and nonheme manganese-catalyzed remote hydroxylation of C–H bonds in nitrogen-containing molecules

J Chen, W Song, J Yao, Z Wu, YM Lee… - Journal of the …, 2023 - ACS Publications
The development of catalytic systems capable of oxygenating unactivated C–H bonds with
excellent site-selectivity and functional group tolerance under mild conditions remains a …

Arginine‐Containing Ligands Enhance H2 Oxidation Catalyst Performance

A Dutta, JAS Roberts, WJ Shaw - Angewandte Chemie, 2014 - Wiley Online Library
Hydrogenase enzymes use Ni and Fe to oxidize H2 at high turnover frequencies (TOF)(up to
10 000 s− 1) and low overpotentials (< 100 mV). In comparison, the fastest reported …

[PDF][PDF] A self-sufficient peroxide-driven hydroxylation biocatalyst

PC Cirino, FH Arnold - Angewandte Chemie International …, 2003 - cheme.caltech.edu
Controlled, selective oxidations of unactivated CÀH bonds are among the most desired
transformations in catalysis.[1] Limitations to chemical oxidation catalysts include low …

Selective hydrogenolysis of C–O bonds using the interaction of the catalyst surface and OH groups

K Tomishige, Y Nakagawa, M Tamura - Selective catalysis for renewable …, 2014 - Springer
Hydrogenolysis of C–O bonds is becoming more and more important for the production of
biomass-derived chemicals. Since substrates originated from biomass usually have high …

Amorphous-crystalline heterostructure: Efficient catalyst for biomass oxidation coupled with hydrogen evolution

J Wu, K Wang, T Yu, S Huang, Z Zhai, H Wen… - Journal of Colloid and …, 2024 - Elsevier
The development of catalysts with high activity, selectivity, and stability is critical for biomass
upgrading coupled with hydrogen evolution. In this study, we present a simple method for …

[HTML][HTML] Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides

M Tan, Y Yang, Y Yang, J Chen, Z Zhang, G Fu… - Nature …, 2022 - nature.com
Spontaneous migration of atomic hydrogen species from metal particles to the surface of
their support, known as hydrogen spillover, has been claimed to play a major role in catalytic …

Selective Catalytic Oxidation of C H Bonds with Molecular Oxygen

E Roduner, W Kaim, B Sarkar, VB Urlacher… - …, 2013 - Wiley Online Library
Although catalytic reductions, cross‐couplings, metathesis, and oxidation of C C double
bonds are well established, the corresponding catalytic hydroxylations of C H bonds in …

Effect of Electronic Structure over Late Transition-Metal M1–N4 Single-Atom Sites on Hydroxyl Radical-Induced Oxidations

J Duan, Y Zhou, Y Ren, F Liu, P Deng, M Yang… - ACS …, 2023 - ACS Publications
Hydroxyl radical (• OH)-induced oxidations are of great importance in chemical
transformations. Carbon-supported late transition-metal single-atom catalysts (SACs) with …

Hydrogenation of Nitroarenes by Onsite-Generated Surface Hydroxyl from Water

Y Wei, S Wang, Y Zhang, M Li, J Hu, Y Liu, J Li… - ACS …, 2023 - ACS Publications
Directly using water as a hydrogen source for hydrogenation of nitroarenes to anilines
(HNA) without using H2 is an ideal reduction reaction route but is limited by unfavorable …