Hydrogen‐Binding‐Initiated Activation of O− H Bonds on a Nitrogen‐Doped Surface for the Catalytic Oxidation of Biomass Hydroxyl Compounds
X Liu, Y Luo, H Ma, S Zhang, P Che… - Angewandte …, 2021 - Wiley Online Library
Hydrogen binding of molecules on solid surfaces is an attractive interaction that can be used
as the driving force for bond activation, material‐directed assembly, protein protection, etc …
as the driving force for bond activation, material‐directed assembly, protein protection, etc …
Hydrogen bonding-assisted and nonheme manganese-catalyzed remote hydroxylation of C–H bonds in nitrogen-containing molecules
J Chen, W Song, J Yao, Z Wu, YM Lee… - Journal of the …, 2023 - ACS Publications
The development of catalytic systems capable of oxygenating unactivated C–H bonds with
excellent site-selectivity and functional group tolerance under mild conditions remains a …
excellent site-selectivity and functional group tolerance under mild conditions remains a …
Arginine‐Containing Ligands Enhance H2 Oxidation Catalyst Performance
Hydrogenase enzymes use Ni and Fe to oxidize H2 at high turnover frequencies (TOF)(up to
10 000 s− 1) and low overpotentials (< 100 mV). In comparison, the fastest reported …
10 000 s− 1) and low overpotentials (< 100 mV). In comparison, the fastest reported …
[PDF][PDF] A self-sufficient peroxide-driven hydroxylation biocatalyst
Controlled, selective oxidations of unactivated CÀH bonds are among the most desired
transformations in catalysis.[1] Limitations to chemical oxidation catalysts include low …
transformations in catalysis.[1] Limitations to chemical oxidation catalysts include low …
Selective hydrogenolysis of C–O bonds using the interaction of the catalyst surface and OH groups
K Tomishige, Y Nakagawa, M Tamura - Selective catalysis for renewable …, 2014 - Springer
Hydrogenolysis of C–O bonds is becoming more and more important for the production of
biomass-derived chemicals. Since substrates originated from biomass usually have high …
biomass-derived chemicals. Since substrates originated from biomass usually have high …
Amorphous-crystalline heterostructure: Efficient catalyst for biomass oxidation coupled with hydrogen evolution
The development of catalysts with high activity, selectivity, and stability is critical for biomass
upgrading coupled with hydrogen evolution. In this study, we present a simple method for …
upgrading coupled with hydrogen evolution. In this study, we present a simple method for …
[HTML][HTML] Hydrogen spillover assisted by oxygenate molecules over nonreducible oxides
M Tan, Y Yang, Y Yang, J Chen, Z Zhang, G Fu… - Nature …, 2022 - nature.com
Spontaneous migration of atomic hydrogen species from metal particles to the surface of
their support, known as hydrogen spillover, has been claimed to play a major role in catalytic …
their support, known as hydrogen spillover, has been claimed to play a major role in catalytic …
Selective Catalytic Oxidation of C H Bonds with Molecular Oxygen
E Roduner, W Kaim, B Sarkar, VB Urlacher… - …, 2013 - Wiley Online Library
Although catalytic reductions, cross‐couplings, metathesis, and oxidation of C C double
bonds are well established, the corresponding catalytic hydroxylations of C H bonds in …
bonds are well established, the corresponding catalytic hydroxylations of C H bonds in …
Effect of Electronic Structure over Late Transition-Metal M1–N4 Single-Atom Sites on Hydroxyl Radical-Induced Oxidations
J Duan, Y Zhou, Y Ren, F Liu, P Deng, M Yang… - ACS …, 2023 - ACS Publications
Hydroxyl radical (• OH)-induced oxidations are of great importance in chemical
transformations. Carbon-supported late transition-metal single-atom catalysts (SACs) with …
transformations. Carbon-supported late transition-metal single-atom catalysts (SACs) with …
Hydrogenation of Nitroarenes by Onsite-Generated Surface Hydroxyl from Water
Y Wei, S Wang, Y Zhang, M Li, J Hu, Y Liu, J Li… - ACS …, 2023 - ACS Publications
Directly using water as a hydrogen source for hydrogenation of nitroarenes to anilines
(HNA) without using H2 is an ideal reduction reaction route but is limited by unfavorable …
(HNA) without using H2 is an ideal reduction reaction route but is limited by unfavorable …