New method of preparation of C2F5Li and its reactions with cyclic imines and lactims: Synthesis of α-pentafluoroethyl proline

NE Shevchenko, VG Nenajdenko… - Journal of Fluorine …, 2008 - Elsevier
Addition of pentafluoroethyllithium to cyclic imines leads to pentafluoroethyl substituted
pyrrolidines, piperidines and azepanes while reaction of cyclic lactims gives rise to 2 …

Pentafluoroethyllithium. Generation and use in synthesis

PG Gassman, NJ O'Reilly - Tetrahedron Letters, 1985 - Elsevier
Tetrahedron Letters,Vol.26,No.43,pp 5243-5246,1985 0040-4039/85 $3.00 + .OO Printed in
Great Britain 01985 Pergamon Press Ltd. P Page 1 Tetrahedron Letters,Vol.26,No.43,pp …

Boron trifluoride-assisted reaction of perfluoroalkyllithiums with imines. A Novel route to perfluoroalkylated amines.

H Uno, Y Shiraishi, K Shimokawa, H Suzuki - Chemistry Letters, 1988 - jlc.jst.go.jp
C 1988 The Chemical Society of Japan Page 1 CHEMISTRY LETTERS, pp. 729-732, 1988.
C 1988 The Chemical Society of Japan Boron Trifluoride-Assisted Reaction of …

Reactions of trifluorovinyllithium and 1-chloro-2, 2-difluorovinyllithium: the synthesis of fluorinated heterocycles

J Burdon, PL Coe, IB Haslock, RL Powell - Journal of fluorine chemistry, 1997 - Elsevier
Trifluorovinyllithium (from 1, 1, 1, 2-tetrafluoroethane [HFC-134a]) reacted with 2-
trifluoromethylaniline at− 78° C to give 1, 2, 3-trifluoroquinolin in moderate to good yield. In a …

Synthesis of medicinally interesting polyfluoro ketones via perfluoroalkyl lithium reagents

CG Kokotos, C Baskakis, G Kokotos - The Journal of Organic …, 2008 - ACS Publications
The addition of (pentafluoroethyl)-and (heptafluoropropyl) lithium to various acyl derivatives
was studied. Weinreb and morpholine amides led to polyfluoro ketones in high to …

An improved cyclisation protocol for the synthesis of δ, δ-difluoro-δ-lactones.

DA Kendrick, M Kolb - Journal of fluorine chemistry, 1989 - Elsevier
An improved procedure for the synthesis of δ, δ-difluoro-°-lactones from 5, 5-difluoro-4-
pentenoic acids is described. The method is illustrated for 2-benzyl-5, 5-difluoro-4-pentenoic …

Hydrofluorocarbon 245fa: a versatile new synthon in alkyne chemistry

AK Brisdon, IR Crossley - Chemical communications, 2002 - pubs.rsc.org
Hydrofluorocarbon 245fa: a versatile new synthon in alkyne chemistry - Chemical
Communications (RSC Publishing) DOI:10.1039/B207979H Royal Society of Chemistry View …

The trifluoromethyl group in organic synthesis. A review

AS Kiselyov, L Strekowski - Organic preparations and procedures …, 1996 - Taylor & Francis
The last two decades have witnessed a tremendous growth of interest in fluoroorganic
compounds.'Numerous treatises on this subject covered various aspects of the chemistry …

Polyfluorobicyclo [2.2. 2] octanes-I 1H-tridecafluorobicyclo [2.2. 2] octane, and some derived compounds

WB Hollyhead, R Stephens, JC Tatlow, WT Westwood - Tetrahedron, 1969 - Elsevier
A Diels-Alder reaction between 1H-heptafluorocyclohexa-1, 3-diene and methyl acrylate
gave two carbomethoxy heptafluorobicyclo [2.2. 2] oct-5-enes. Cobaltic fluoride fluorination …

[引用][C] Triflamides: Elimination of the triflyl anion versus substitution of the trifluoromethide group

S Bozec-Ogor, V Salou-Guiziou, JJ Yaouanc… - Tetrahedron letters, 1995 - Elsevier
Triflamides : Elimination of the Triflyl Anion versus Substitution of the Trifluoromethide Group.
Page 1 Pergamon 0040-4039(95 )01266-4 Tetrahedron Letters, Vol. 36, No. 34, pp. 6063-6066 …