A comprehensive mathematical model of water splitting in bipolar membranes: Impact of the spatial distribution of fixed charges and catalyst at bipolar junction

SA Mareev, E Evdochenko, M Wessling… - Journal of Membrane …, 2020 - Elsevier
Bipolar ion-exchange membranes (BPM) have a long history and many uses. Still, the
number of applications continues to grow every year, as does the interest in a better …

[HTML][HTML] Describing ion transport and water splitting in an electrodialysis stack with bipolar membranes by a 2-D model: Experimental validation

T León, J López, R Torres, J Grau, L Jofre… - Journal of Membrane …, 2022 - Elsevier
Electrodialysis with bipolar membranes (EDBM) has drawn attention motivated by their
application in generating reagents from salts. Due to the water splitting (WS) occurring at the …

Origin of limiting and overlimiting currents in bipolar membranes

R Pärnamäe, M Tedesco, MC Wu… - Environmental …, 2023 - ACS Publications
Bipolar membranes (BPMs), a special class of ion exchange membranes with the unique
ability to electrochemically induce either water dissociation or recombination, are of growing …

Heterogeneous bipolar membranes and their application in electrodialysis

V Zabolotskii, N Sheldeshov, S Melnikov - Desalination, 2014 - Elsevier
Over the last 50 years, ion exchange membranes have evolved from a laboratory tool to
industrial products with significant technical and commercial impacts. Bipolar membranes …

Ion transport mechanisms in bipolar membranes for (photo) electrochemical water splitting

DA Vermaas, S Wiegman, T Nagaki… - Sustainable Energy & …, 2018 - pubs.rsc.org
Bipolar membranes (BPMs) have attracted growing interest in electrochemical and
photoelectrochemical systems, as they allow the unique ability to pair two different …

Experimental and theoretical investigations of steady and transient states in systems of ion exchange bipolar membranes

HD Hurwitz, R Dibiani - Journal of membrane science, 2004 - Elsevier
The electrochemical characteristics of one commercial bipolar ion exchange membrane and
of two home-made bipolar membranes are investigated over a range of current densities up …

Water splitting at an anion-exchange membrane as studied by impedance spectroscopy

E Kniaginicheva, N Pismenskaya, S Melnikov… - Journal of Membrane …, 2015 - Elsevier
Electrochemical impedance spectroscopy (EIS) is largely used in studying water splitting
reaction in bipolar membranes (BPMs). This reaction is also very important in monopolar …

The balance of electric field and interfacial catalysis in promoting water dissociation in bipolar membranes

Z Yan, L Zhu, YC Li, RJ Wycisk, PN Pintauro… - Energy & …, 2018 - pubs.rsc.org
The lamination of a cation exchange layer (CEL) and an anion exchange layer (AEL) to form
a hybrid bipolar membrane (BPM) can have several unique advantages over conventional …

Current‐voltage curves of bipolar membranes

P Ramirez, HJ Rapp, S Reichle, H Strathmann… - Journal of applied …, 1992 - pubs.aip.org
Bipolar membranes consist of a layered ion‐exchange structure composed of a cation
selective membrane joined to an anion selective membrane. They are analogous to …

Understanding multi-ion transport mechanisms in bipolar membranes

JC Bui, I Digdaya, C Xiang, AT Bell… - ACS Applied Materials & …, 2020 - ACS Publications
Bipolar membranes (BPMs) have the potential to become critical components in
electrochemical devices for a variety of electrolysis and electrosynthesis applications …