Surface premelting of water ice

B Slater, A Michaelides - Nature Reviews Chemistry, 2019 - nature.com
Frozen water has a quasi-liquid layer at its surface that exists even well below the bulk
melting temperature; the formation of this layer is termed premelting. The nature of the …

Why is it so difficult to identify the onset of ice premelting?

Y Qiu, V Molinero - The journal of physical chemistry letters, 2018 - ACS Publications
Premelting of ice at temperatures below 0° C is of fundamental importance for environmental
processes. Various experimental techniques have been used to investigate the temperature …

Surface premelting of ice

Y Li, GA Somorjai - The Journal of Physical Chemistry C, 2007 - ACS Publications
In this review, we summarize the available experimental data from recently developed
molecular level techniques on the surface structure, surface premelting layer thickness, and …

Thermodynamic origin of surface melting on ice crystals

K Murata, H Asakawa, K Nagashima… - Proceedings of the …, 2016 - National Acad Sciences
Since the pioneering prediction of surface melting by Michael Faraday, it has been widely
accepted that thin water layers, called quasi-liquid layers (QLLs), homogeneously and …

Local ice-like structure at the liquid water surface

NL Odendahl, PL Geissler - Journal of the American Chemical …, 2022 - ACS Publications
Experiments and computer simulations have established that liquid water's surfaces can
deviate in important ways from familiar bulk behavior. Even in the simplest case of an air …

Surface melting of ice

L Makkonen - The Journal of Physical Chemistry B, 1997 - ACS Publications
The present theories of surface premelting are based on the assumed mechanism whereby
a liquid layer is formed because the free energy of the surface is thus minimized. It is shown …

Heterogeneous ice nucleation: Interplay of surface properties and their impact on water orientations

B Glatz, S Sarupria - Langmuir, 2018 - ACS Publications
Ice is ubiquitous in nature, and heterogeneous ice nucleation is the most common pathway
of ice formation. How surface properties affect the propensity to observe ice nucleation on …

The many faces of heterogeneous ice nucleation: Interplay between surface morphology and hydrophobicity

M Fitzner, GC Sosso, SJ Cox… - Journal of the American …, 2015 - ACS Publications
What makes a material a good ice nucleating agent? Despite the importance of
heterogeneous ice nucleation to a variety of fields, from cloud science to microbiology, major …

Is ice nucleation from supercooled water insensitive to surface roughness?

JM Campbell, FC Meldrum… - The Journal of Physical …, 2015 - ACS Publications
There is much evidence that nucleation of liquid droplets from vapor as well as nucleation of
crystals from both solution and vapor occurs preferentially in surface defects such as pits …

Heterogeneous surface crystallization observed in undercooled water

RA Shaw, AJ Durant, Y Mi - The Journal of Physical Chemistry B, 2005 - ACS Publications
We report laboratory observations of higher freezing temperatures when an ice-forming
nucleus is near the surface of an undercooled water drop than when the nucleus is …