The favorable exploitation of carbon nitride (CN) materials in photocatalysis for organic
synthesis requires the appropriate fine-tuning of the CN structure. Here, we present a deep …

In this work, we explored a post-synthetic modification of the well-known graphitic carbon
nitride (g-CN) by means of an “amorphization” treatment and evaluate the resulting change …

Efficient catalytic methods for the trifluoromethylation of (hetero) arenes are of particular
importance in organic and pharmaceutical manufacturing. However, many existing protocols …

A new photocatalytic reaction process is described that cyano groups (single bondCN) are
successfully grafted on carbon nitride (gC 3 N 4 materials). The cyano group substitutes the …

C–F functionalizations that provide C–C bonds are challenging synthetic transformations,
due in part to the large C–F bond strength, short bond length, nonpolarizable nature, the …

The development of novel chemical transformations calls for environmentally friendly
synthetic methods. Visible light photoredox catalysis has gained attention as a versatile tool …

Heterogeneous catalysis for trifluoromethylations and perfluoroalkylations has been
performed. Through the usage of cheap, metal‐free and recyclable mesoporous graphitic …

Employing a photocatalyst system based on copper and BINAP, visible light-mediated
perfluoroalkylative carbonylation of unactivated alkenes has been developed. The method …

With the continued interest in the properties of the difluoromethyl (CF2H) group, small
molecules with alkyl-CF2H motifs have gained increasing attention. However, concise and …

The use of amine‐rich N‐doped carbon nanodots (NCNDs) for the photochemical radical
perfluoroalkylation of organic compounds is reported. This operationally simple approach …