Sugar-induced conformational changes in boronic acid-appended poly (L-and D-lysine) s and sugar-controlled orientation of a cyanine dye on the polymers

T Kimura, S Arimori, M Takeuchi, T Nagasaki… - Journal of the …, 1995 - pubs.rsc.org
Poly (L-and D-lysine) s have been modified with para-or meta-phenylboronic acid
derivatives which act as sugar-binding sites (L-1 and D-1 for the para-isomer and L-2 for the …

Sugar-induced color and orientation changes in a cyanine dye bound to boronic-acid-appended poly (L-lysine)

T Kimura, M Takeuchi, T Nagasaki, S Shinkai - Tetrahedron letters, 1995 - Elsevier
A cyanine dye (2) can be orientated on boronic-acid-modified poly (L-and D-lysine) s (L-and
D-1, respectively) in the presence of saccharides. The main driving-force for the association …

Influence of Added Saccharides on the Conformation of Boronic-Acid-Appended Poly (L-lysine). Attempts to Control a Helix-Coil Transition by Sugars.

T Nagasaki, T Kimura, S Arimori, S Shinkai - Chemistry letters, 1994 - jlc.jst.go.jp
Poly (L-and D-lysine) s (L-and D-1, respectively) were modified with a phenylboronic acid
derivative which acts as a sugar-binding site. When monosaccharides were added to the L-1 …

Novel saccharide-induced conformational changes in a boronic acid-appended poly (L-lysine) as detected by circular dichroism and fluorescence

H Kobayashi, K Nakashima, E Ohshima… - Journal of the …, 2000 - pubs.rsc.org
Poly (L-lysine) has been modified with a 4-phenylboronic acid derivative which acts as a
sugar-binding site and a dansyl group which acts as a fluorescence probing site. The helix …

Unique property of cyanine dyes on charged poly (L-lysine)

M Shibata, H Ihara, C Hirayama - Polymer, 1993 - Elsevier
Charged poly (l-lysine) forms a random coil in water (pH 7) and an α-helix in methanol.
Cyanine (NK-2012) dyes combine with these charged poly (l-lysine) s to produce S-chiral …

Conformational Aspects of Polypeptide Structure. XXXIV. Amino Acid Substituted Poly-L-Lysines

N Anand, N Murthy, F Naider, M Goodman - Macromolecules, 1971 - ACS Publications
An investigation was carried out on several poly-L-lysines containing amino acid
substituents on the Ne position. The conformations of these polypeptides were examined …

Salt effect on the conformation of an alternating copolymer of L-leucine and L-lysine

G Ebert, Y Kuroyanagi - Polymer, 1982 - Elsevier
Abstract The 'statistical'copoly (l-leucyl-l-lysine) is shown to undergo a coil to α-helix
transition by either adding salt or raising the pH. However, the corresponding alternating …

Carrier design: Conformational studies of amino acid (X) and oligopeptide (X‐DL‐Alam) substituted poly(L‐lysine)

G Mezö, J Kajtár, F Hudecz… - … : Original Research on …, 1993 - Wiley Online Library
The present study was undertaken to examine the influence of the reversal of the sidechain
sequential order on the conformation of branched polypeptides. At the same time, the …

Influence of isopropanol‐water solvent mixtures on the conformation of poly‐L‐lysine

M Barteri, B Pispisa - Biopolymers: Original Research on …, 1973 - Wiley Online Library
The helix–coil transition of poly‐l‐lysine (PLL) in water–isopropanol solvent mixtures has
been investigated at room temperature by circular dichroism measurements. Within the …

Helix → β conformational transition of poly(L‐lysine) on dye binding

PV Scaria, M Atreyi, MVR Rao - … : Original Research on …, 1986 - Wiley Online Library
Binding of an azo dye, 4′‐dimethyl amino azo benzene‐4‐carboxylic acid (DAAC) to poly (l‐
lysine)(PLL) in basic aqueous solutions at 20° C has been studied. The azo dye was found …