Structural and Chemical Insights into Designer Defects in Tetragonal-like Epitaxial BiFeO3 Thin Films

Y Sakamoto, JE Daniels, N Valanoor… - The Journal of …, 2024 - ACS Publications
In ferroelectric oxides, it is well-known that defect engineering can be exploited to stabilize
novel polar phases. In bismuth ferrite (BiFeO3; BFO) epitaxial films, coherent bismuth oxide …

Influence of chemical solution growth and vacuum annealing on the properties of (100) pseudocubic oriented BiFeO3 thin films

S Nandy, C Sudakar - Journal of Applied Physics, 2019 - pubs.aip.org
BiFeO 3 (BFO), a Pb-free perovskite oxide, is being explored for its potential use in a
multitude of applications. We report on the oriented growth of BFO thin films using a facile …

Thickness dependence of crystal and electronic structures within heteroepitaxially grown thin films

IT Bae, H Naganuma, T Ichinose, K Sato - Physical Review B, 2016 - APS
Crystal and electronic structures of BiFe O 3 thin films (∼ 10 and∼ 300 nm) grown on SrTi O
3 substrate have been investigated in terms of BiFe O 3 film thickness dependence using the …

Bandgap engineering strategy through chemical strain and oxygen vacancies in super-tetragonal BiFeO 3 epitaxial films

J Ding, H Li, G Xi, J Tu, J Tian, L Zhang - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
The wide band gap of bismuth ferrate-based materials limits their application in
optoelectronic devices, and how to achieve band gap modulation in the simplest manner is …

The atomic configuration and metallic state of extrinsic defects in Nb-doped BiFeO3 thin films

L Liao, Q Yang, C Cai, Y Zhou, H Sun, X Huang… - Acta Materialia, 2024 - Elsevier
Defects in ferroelectric materials can cause microscopic strain and electron doping, which
opens up new possibilities for unique physical properties in nanoelectronics. However …

Manipulating the Ferroelectric Domain States and Structural Distortion in Epitaxial BiFeO3 Ultrathin Films via Bi Nonstoichiometry

S Tian, C Wang, Y Zhou, X Li, P Gao… - … applied materials & …, 2018 - ACS Publications
Exploring and manipulating domain configurations in ferroelectric thin films are of critical
importance for the design and fabrication of ferroelectric heterostructures with a novel …

Origin of antipolar clusters in BiFeO3 epitaxial thin films

B Liu, C Yang, X Li, C Wang, G Liu, H Yang… - Journal of the European …, 2018 - Elsevier
The microstructure of BiFeO 3 (BFO) thin films is investigated using high-resolution
transmission electron microscopy. Both (001)-and (101)-type domain boundaries are found …

Nanoscale Structural and Chemical Properties of Antipolar Clusters in Sm-Doped BiFeO3 Ferroelectric Epitaxial Thin Films

CJ Cheng, AY Borisevich, D Kan, I Takeuchi… - Chemistry of …, 2010 - ACS Publications
The local atomic structure and nanoscale chemistry of an antipolar phase in Bi0. 9Sm0.
1FeO3 epitaxial thin films are examined by an array of transmission electron microscopy …

Effect of single point defect on local properties in BiFeO3 thin film

X Li, M Li, X Li, S Tian, AY Abid, N Li, J Wang, L Zhang… - Acta materialia, 2019 - Elsevier
Point defects commonly exist in artificially prepared ferroelectric oxide films. Here, the local
polarization characteristics around a single point defect of Bi substitution in the Fe sites …

Elucidation of crystal and electronic structures within highly strained BiFeO3 by transmission electron microscopy and first-principles simulation

IT Bae, A Kovács, HJ Zhao, J Íñiguez, S Yasui… - Scientific Reports, 2017 - nature.com
Crystal and electronic structures of~ 380 nm BiFeO3 film grown on LaAlO3 substrate are
comprehensively studied using advanced transmission electron microscopy (TEM) …