Chiral Macromolecules and Supramolecular Assemblies: Synthesis, Properties and Applications

M Zhang, M Kim, W Choi, J Choi, DH Kim, Y Liu… - Progress in Polymer …, 2024 - Elsevier
Chirality, an inherent characteristic observed throughout nature, plays a pivotal role across a
wide range of scales, from subatomic to galactic, and holds significance in myriad scientific …

Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Supramolecular polymerization of chiral molecules devoid of chiral centers

WR Henderson, RK Castellano - Polymer International, 2021 - Wiley Online Library
The iterative association of monomer units through noncovalent interactions often leads to
chiral supramolecular polymers. Monomers comprising these materials can be further …

Modulating the chiroptical response of chiral polymers with extended conjugation within the structural building blocks

JP Joseph, SR Abraham, A Dutta, A Baev… - The Journal of …, 2022 - ACS Publications
Advancing the emerging area of chiral photonics requires modeling-guided concepts of
chiral material design to enhance optical activity and associated optical rotatory dispersion …

[HTML][HTML] Preparation of chiral polymers: Precise chirality transfer from natural species to achiral artificial polymers

T Miao, X Cheng, Y Guo, G Zhang, W Zhang - Giant, 2023 - Elsevier
The synthesis of chiral substances, especially chiral polymers is currently one of the hottest
issues in the field of chiral materials and chemistry due to their unique structural …

Supramolecular chiral polymeric aggregates: Construction and applications

G Zhang, X Cheng, Y Wang, W Zhang - Aggregate, 2023 - Wiley Online Library
Inspired by the mystery of natural homochirality, the design and construction of artificial
chiral systems with special functions including mechanics, chiroptical devices, and chiral …

Chiral materials: progress, applications, and prospects

X Niu, R Zhao, S Yan, Z Pang, H Li, X Yang, K Wang - Small, 2023 - Wiley Online Library
Chirality is a universal phenomenon in molecular and biological systems, denoting an
asymmetric configurational property where an object cannot be superimposed onto its mirror …

Construction of supramolecular chirality in polymer systems: chiral induction, transfer and application

XX Cheng, TF Miao, L Yin, W Zhang, XL Zhu - Chinese Journal of Polymer …, 2021 - Springer
Chirality, commonly found in organisms, biomolecules and nature such as L-amino acids
and D-sugars, has been extensively studied in chemistry and biomedical science. Hence …

Helical assemblies of one-dimensional supramolecular polymers composed of helical macromolecules: generation of circularly polarized light using an infinitesimal …

T Ikai, M Okubo, Y Wada - Journal of the American Chemical …, 2020 - ACS Publications
We report the synthesis of one-dimensional supramolecular polymers composed of one-
handed helical macromolecules bearing fluorescent pendant groups and the generation of …

Self-assembled chiral materials from achiral components or racemates

B Chang, X Li, T Sun - European Polymer Journal, 2019 - Elsevier
The emergence of chirality effect at extended scales of self-assembled systems from achiral
or racemic precursors has long been a matter of curiosity for scientists, because the …