Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Radical/radical cross-coupling represents a straightforward way for the construction of new
chemical bonds in theory and has received more and more attention over the past several …

The persistent radical effect (PRE) is a principle that explains the highly selective cross‐
coupling between a persistent and a transient radical when both species are formed at …

Many kinds of radicals are stable enough to isolate, handle, and store without any special
precautions. The diversity in molecular architectures of these stable radicals is sufficiently …

Radicals are of fundamental relevance to areas as varied as organic synthesis,
homogeneous catalysis, the chemistry of metabolisms, the degredation of aerobic cells, the …

The area of catalysis of radical reactions has recently flourished. Various reaction conditions
have been discovered and explained in terms of catalytic cycles. These cycles rarely stand …

Since Friedrich Wöhler's groundbreaking synthesis of urea in 1828, organic synthesis over
the past two centuries has predominantly relied on the exploration and utilization of …

Radical species are significant in modern chemistry. Their unique chemical bonding and
novel physicochemical properties play significant roles not only in fundamental chemistry …

Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …

This review summarizes the current status of transition metal catalyzed reactions involving
radical intermediates in organic chemistry. This part focuses on radical-based methods …