New catalytic strategies that leverage single-electron redox events have provided chemists
with useful tools for solving synthetic problems. In this context, Ti offers opportunities that are …

Titanium redox catalysis: insights and applications of an earth-abundant base metal - Dalton
Transactions (RSC Publishing) DOI:10.1039/C7DT02319G Royal Society of Chemistry View …

We describe a combination of catalysts that allows the coupling of titanocene (III) catalysis
with photoredox catalysis. Oxidation of radical intermediates by a photoredox catalyst opens …

The preparatively important catalytic opening of epoxides to β-titanoxy radicals via single-
electron transfer (SET) is described. These radicals can be reduced to alcohols or …

Bis (cyclopentadienyl) titanium (III) chloride(Nugent s reagent)[1] is an efficient single-
electron reductant and has been used as a versatile tool in organic synthesis,[2, 3] owing to …

Organic radicals are generally short-lived intermediates with exceptionally high reactivity.
Strategically, achieving synthetically useful transformations mediated by organic radicals …

COMMUNICATIONS Page 1 COMMUNICATIONS Angew. Chem. Int. Ed. 1998, 37, No. 1/2
WILEY-VCH Verlag GmbH, D-69451 Weinheim, 1998 1433-7851/98/3701-0101 $ 17.50+.50/0 …

This review summarizes the current status of transition metal catalyzed reactions involving
radical intermediates in organic chemistry. This part focuses on radical-based methods …

Alkyl chlorides are common functional groups in synthetic organic chemistry. However, the
engagement of unactivated alkyl chlorides, especially tertiary alkyl chlorides, in transition …

An atom‐economical and catalytic arylation of epoxide‐derived radicals is described. The
key step of the catalytic system is a sequential electron and proton transfer for the …