Sulfur has been important in dynamic covalent chemistry (DCC) since the beginning of the
field. Mainly as part of disulfides and thioesters, dynamic sulfur‐based bonds (DSBs) have a …

A Tutorial Review of the subtle supramolecular interactions influencing the outcomes of
equilibrating systems, focusing on the dynamic covalent chemistry (DCC) of disulfide …

Organosulfur functionalities are ubiquitous in nature, pharmaceuticals, agrochemicals,
materials and flavourants. Historically, these moieties were introduced almost exclusively …

Controlling selectivity is of central importance to radical chemistry. However, the highly
reactive and unstable radical intermediates make this task especially challenging. Herein, a …

A reversible covalent bond exchange of thiols, β-sulfido-α, β-unsaturated carbonyls, and
dithianes has been studied in DMSO and D2O/DMSO mixtures. The equilibrium between …

Aryl sulfonyl chlorides (eg Ts‐Cl) are beloved of organic chemists as the most commonly
used SVI electrophiles, and the parent sulfuryl chloride, O2SVICl2, has also been relied on …

Reactive sulfur species (RSS) are biologically important molecules. Among them, H2S,
hydrogen polysulfides (H2Sn, n> 1), persulfides (RSSH), and HSNO are believed to play …

Organic compounds possessing S–S bonds, often called disulfides or more specifically
disulfanes, have been widely applied in various fields ranging from biochemistry to different …

During the last decade, radical reactions have gained wide acceptance as efficient ways to
build complex frameworks under mild conditions.[1] This ability is largely a consequence of …

The use of sulfinic acids and their salts continues to be extensively developed in organic
chemistry. This is attributable to their dual capacity for acting as nucleophilic or electrophilic …