Influence of electronic delocalization in metal-to-ligand charge transfer excited states

GF Strouse, JR Schoonover, R Duesing… - Inorganic …, 1995 - ACS Publications
Ru (dmb) 2](PF6) 4 and [(bpy) 20s (ii-bbpe) 0s (bpy) 2](PF6) 4)(bpy is 2, 2'-bipyridine, dmb is
4, 4'-dimethyl-2, 2'-bipyridine, bbpe is trans-1, 2-bis-(4-(4'-methyl)-2, 2'-bipyridyl) ethene) …

Rigid medium stabilization of metal-to-ligand charge transfer excited states

DW Thompson, CN Fleming, BD Myron… - The Journal of …, 2007 - ACS Publications
The salts [Ru (bpy) 3](PF6) 2, cis-[Ru (bpy) 2 (py) 2](PF6) 2, trans-[Ru (bpy) 2 (4-Etpy)
2](PF6) 2,[Ru (tpy) 2](PF6) 2, and [Re (bpy)(CO) 3 (4-Etpy)](PF6)(bpy= 2, 2 '-bipyridine, py …

Ultrafast Dynamics in the Metal-to-Ligand Charge Transfer Excited-State Evolution of [Ru(4,4'-diphenyl-2,2'-bipyridine)3]2+

NH Damrauer, JK McCusker - The Journal of Physical Chemistry …, 1999 - ACS Publications
The transition metal complexes [Ru (dmb) 3] 2+ and [Ru (dpb) 3] 2+, where dmb is 4, 4 '-
dimethyl-2, 2 '-bipyridine and dpb is 4, 4 '-diphenyl-2, 2 '-bipyridine, have been studied by …

[Ru (bpy) 3] 2+∗ revisited. Is it localized or delocalized? How does it decay?

P Dongare, BDB Myron, L Wang, DW Thompson… - Coordination Chemistry …, 2017 - Elsevier
The issue of localization/delocalization of electron spin density in Metal-to-Ligand Charge
Transfer (MLCT) excited states of [Ru (bpy) 3] 2+(bpy= 2, 2′-bipyridine) has been debated …

Mid-Infrared Spectrum of [Ru(bpy)3]2+

KM Omberg, JR Schoonover… - Journal of the …, 1997 - ACS Publications
The first time-resolved infrared difference spectra for metal-to-ligand charge transfer (MLCT)
excited states in the fingerprint region from 1400 to 1625 cm-1 are reported for [Ru (bpy) 3] …

Intramolecular, photoinduced electron transfer in ruthenium (II) bipyridine-quinone complexes

KA Opperman, SL Mecklenburg, TJ Meyer - Inorganic Chemistry, 1994 - ACS Publications
Intramolecular electron transfer quenching following metal-to-ligand charge transfer (MLCT)
excitation of complexes of Run containing the ligand N-((4'-methyl-2, 2'-bipyridyl)-4-methyl) …

Characteristics and Properties of Metal-to-Ligand Charge-Transfer Excited States in 2, 3-Bis (2-pyridyl) pyrazine and 2, 2 '-Bypyridine Ruthenium Complexes …

DS Seneviratne, MJ Uddin… - Inorganic …, 2002 - ACS Publications
The absorption, emission, and infrared spectra, metal (Ru) and ligand (PP) half-wave
potentials, and ab initio calculations on the ligands (PP) are compared for several [L n Ru …

The effect on MLCT excited states of electronic delocalization in the acceptor ligand

S Boyde, GF Strouse, WE Jones Jr… - Journal of the American …, 1990 - ACS Publications
The metal to ligand charge transfer (MLCT) excited states of [Ru (bpy) 3] 2+(bpy= 2, 2'-
bipyridyl) and related polypyridyl complexes of Ru”, Os11, or Re1 have been utilized …

Directed, intramolecular electron transfer in mixed-valence dimers

JC Curtis, JS Bernstein, TJ Meyer - Inorganic Chemistry, 1985 - ACS Publications
Ru (III) intervalence-transfer (IT) bands are observed. Photolysisinto either the 7r*(bpy)*- dir
(RunCl (bpy) 2) chromophore for the Ru (II)-Ru (II) dimers or the ir*(L)*-dir (RunCl (dpte) 2) …

Highly Solvent Dependent Luminescence from [Ru(bpy)n(dppp2)3−n]2+ (n = 0−2)

Y Sun, C Turro - Inorganic chemistry, 2010 - ACS Publications
The photophysical properties of a series of ruthenium (II) complexes possessing the dppp2
(dppp2= pyrido [2′, 3′: 5, 6] pyrazino [2, 3-f][1, 10] phenanthroline) ligand,[Ru (bpy) n …