The synthesis of polyolefin graft copolymers by reactive extrusion

G Moad - Progress in Polymer Science, 1999 - Elsevier
The synthesis of polyolefin graft copolymers by reactive extrusion or other forms of melt
phase processing is reviewed. Primary concerns are the structures of the graft copolymers …

Exchange and free radical grafting reactions in reactive extrusion

GH Hu, JJ Flat, M Lambla - … Chemie. Macromolecular Symposia, 1993 - Wiley Online Library
The potential of two types of reactions for reactive extrusion was evaluated in our laboratory:
exchange reactions of copolyesters and free radical grafting of monomers onto polyolefins …

Properties of crosslinked polyolefin-based materials

I Chodák - Progress in Polymer Science, 1995 - Elsevier
Crosslinking is a broadly used method for the modification of polymer properties. This
process involves the formation of tridimensional structures-gels-causing substantial changes …

Control of macromolecular architecture during the reactive functionalization in the melt of olefin polymers

E Passaglia, S Coiai, S Augier - Progress in Polymer Science, 2009 - Elsevier
The functionalization of polyolefins is a useful methodology to chemically convert these
extremely important commodities into value-added polymers by generating materials with …

Solid phase graft copolymerization. I. Effect of initiator and catalyst

R Rengarajan, M Vicic, S Lee - Journal of applied polymer …, 1990 - Wiley Online Library
Polypropylene–maleic anhydride (PP–MA) graft copolymers were produced from isotactic
homopolymer polypropylene (molecular weight> 150,000) utilizing the technique of solid …

Free radical graft polymerization and copolymerization at higher temperatures

KE Russell - Progress in polymer science, 2002 - Elsevier
Recent work on the graft polymerization of vinyl monomers to polyolefins and model
hydrocarbons is reviewed. For practical reasons, these reactions are performed at high …

Functionalization of polyethylenes and their use in reactive blending

NC Liu, WE Baker, KE Russell - Journal of applied polymer …, 1990 - Wiley Online Library
The grafting of maleic anhydride (MAn) to low density polyethylenes (PEs) dissolved in 1, 2‐
dichlorobenzene (DCB) has been studied. Grafting was successful at temperatures of about …

Functionalization of polyesters with maleic anhydride by reactive extrusion

R Mani, M Bhattacharya, J Tang - Journal of Polymer Science …, 1999 - Wiley Online Library
Maleic anhydride (MAn) was grafted onto aliphatic and aromatic/aliphatic copolyesters by
reactive extrusion in the presence of a free radical initiator using a twin‐screw extruder. The …

[PDF][PDF] Synthesis of poly (olefin) graft copolymers by a combination of metallocene and “living” free radical polymerization techniques

UM Stehling, EE Malmström, RM Waymouth… - …, 1998 - polymer.chem.cmu.edu
The development of novel synthetic methods is creating new opportunities for the
preparation of macromolecules with defined architectures and controlled physical …

Graft copolymer modification of polyethylene–polystyrene blends. I. Graft preparation and characterization

CE Locke, DR Paul - Journal of Applied Polymer Science, 1973 - Wiley Online Library
The preparation and characterization of styrene–low‐density polyethylene graft copolymers
for addition to blends of polyethylene and polystyrene to improve blend mechanical …