Four-coordinate dimethylgallium complexes were prepared by the reaction of
dimethylgallium hydroxide with bidentate Lewis bases and evaluated for their stability …

New N4O2-donor acyclic chelators 2-[[2-[2-(3, 5-dimethylpyrazol-1-yl) ethyl-[2-[(2-
hydroxyphenyl) methylamino] ethyl] amino] ethylamino] methyl] phenol (H2Lpz*, NH) and 2 …

Two new gallium (II) derivatives,[GaCl (acac)] 2 (acac= acetylacetonate and [GaCl (tmhd)] 2
(tmhd= 2, 2, 6, 6-tetramethyl-3, 5-heptanedionate), have been prepared and characterized …

The bis (oxazolinato) dimethylgallium complexes [{BOX‐Me2} GaMe2](2a) and [{BOX‐(S)‐
iPr} GaMe2](2b) are easily obtained in nearly quantitative yield by a methane elimination …

A survey of our recent work on organoaluminum and organogallium hydrides is presented.
Three types of ligand system have been employed for the stabilization of monomeric …

The affinities and selectivities of lanthanide complexes with open coordination sites for
anions vary considerably with the chelate. In order to determine the effect of the stability of a …

In an effort to explore novel ligand scaffolds for stable and inert lanthanide complexation in
magnetic resonance imaging contrast agent research, three chiral ligands containing a …

The reactions of (2, 6-Mes2C6H3) 2GaCl (2) with LiMe, Li-t-Bu, and LiHBEt3 afforded the bis
(terphenyl) gallium compounds (2, 6-Mes2C6H3) 2GaMe (3),(2, 6-Mes2C6H3) 2Ga-t-Bu (4) …

Complexes of Ga3+, a d10 metal ion which lacks ligand-field-stabilization energy, are
considered labile. In fact, hexaaquagallium (III) has a ligand exchange rate of 403 s-1, 2.5 …

(BH4) 2] with a pentacoordinate gallium atom. 9 We were particularly interested in
developing a thermally stable organo-metallic compound with a terminal GaH2 group in …