Is ice nucleation by organic crystals nonclassical? An assessment of the monolayer hypothesis of ice nucleation

AK Metya, V Molinero - Journal of the American Chemical Society, 2021 - ACS Publications
Potent ice nucleating organic crystals display an increase in nucleation efficiency with
pressure and memory effect after pressurization that set them apart from inorganic …

[HTML][HTML] Unravelling the origins of ice nucleation on organic crystals

GC Sosso, TF Whale, MA Holden, P Pedevilla… - Chemical …, 2018 - pubs.rsc.org
Organic molecules such as steroids or amino acids form crystals that can facilitate the
formation of ice–arguably the most important phase transition on earth. However, the origin …

Ice nucleation efficiency of hydroxylated organic surfaces is controlled by their structural fluctuations and mismatch to ice

Y Qiu, N Odendahl, A Hudait, R Mason… - Journal of the …, 2017 - ACS Publications
Heterogeneous nucleation of ice induced by organic materials is of fundamental importance
for climate, biology, and industry. Among organic ice-nucleating surfaces, monolayers of …

[HTML][HTML] The role of structural order in heterogeneous ice nucleation

GC Sosso, P Sudera, AT Backes, TF Whale… - Chemical …, 2022 - pubs.rsc.org
The freezing of water into ice is a key process that is still not fully understood. It generally
requires an impurity of some description to initiate the heterogeneous nucleation of the ice …

The many faces of heterogeneous ice nucleation: Interplay between surface morphology and hydrophobicity

M Fitzner, GC Sosso, SJ Cox… - Journal of the American …, 2015 - ACS Publications
What makes a material a good ice nucleating agent? Despite the importance of
heterogeneous ice nucleation to a variety of fields, from cloud science to microbiology, major …

An insight into the ice nucleation process via design of crystalline ice nucleators of variable size

J Majewski, R Popovitz-Biro, R Edgar… - The Journal of …, 1997 - ACS Publications
Monolayers of the long-chain alcohols on water promote nucleation of ice. In order to
determine the minimum size of crystalline alcohol monolayer domains that induce ice …

Reaction coordinate for ice crystallization on a soft surface

L Lupi, R Hanscam, Y Qiu… - The journal of physical …, 2017 - ACS Publications
The control of assembly and crystallization of molecules is becoming increasingly important
in chemistry, engineering, and materials sciences. Crystallization is also central to …

What determines the ice polymorph in clouds?

A Hudait, V Molinero - Journal of the American Chemical Society, 2016 - ACS Publications
Ice crystals in the atmosphere nucleate from supercooled liquid water and grow by vapor
uptake. The structure of the ice polymorph grown has strong impact on the morphology and …

Heterogeneous ice nucleation controlled by the coupling of surface crystallinity and surface hydrophilicity

Y Bi, R Cabriolu, T Li - The Journal of Physical Chemistry C, 2016 - ACS Publications
The microscopic mechanisms controlling heterogeneous ice nucleation are complex and
remain poorly understood. Although good ice nucleators are generally believed to match ice …

Formation of stacking faults during ice growth on hexagonal and cubic substrates

MA Carignano - The Journal of Physical Chemistry C, 2007 - ACS Publications
We present a molecular dynamics simulation study of ice growth from supercooled water in
contact with:(i) the basal plane of hexagonal ice and (ii) the (111) plane of cubic ice. We …