Chiral hypervalent iodines: active players in asymmetric synthesis

A Parra - Chemical reviews, 2019 - ACS Publications
Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …

Asymmetric iodine catalysis-mediated enantioselective oxidative transformations

A Claraz, G Masson - Organic & biomolecular chemistry, 2018 - pubs.rsc.org
The implementation of chiral iodine catalysis has tremendously been developed in the field
of asymmetric synthesis over the past decade. It enables the stereoselective creation of C–O …

Chiral hypervalent iodine reagents: synthesis and reactivity

A Parra, S Reboredo - Chemistry–A European Journal, 2013 - Wiley Online Library
Chiral hypervalent iodine chemistry has been steadily increasing in importance in recent
years. This review catalogues enantioselective transformations triggered by chiral …

Structurally defined molecular hypervalent iodine catalysts for intermolecular enantioselective reactions

S Haubenreisser, TH Wöste, C Martínez… - Angewandte Chemie …, 2016 - Wiley Online Library
Molecular structures of the most prominent chiral non‐racemic hypervalent iodine (III)
reagents to date have been elucidated for the first time. The formation of a chirally induced …

Reagent and catalyst design for asymmetric hypervalent iodine oxidations

F Berthiol - Synthesis, 2015 - thieme-connect.com
In this review are compiled the different possible transformations using environmentally
benign chiral hypervalent iodine reagents and catalysts. Herein is presented an overview of …

[PDF][PDF] Chiral hypervalent iodine reagents in asymmetric reactions

H Liang, MA Ciufolini - Angewandte Chemie International Edition, 2011 - academia.edu
Hypervalent iodine reagents are unusually effective promoters of transformations that would
be difficult, perhaps impossible, to accomplish otherwise. Low toxicity, a favorable safety …

Enantioselective iodine (I/III) catalysis in organic synthesis

A Flores, E Cots, J Bergès… - Advanced Synthesis & …, 2019 - Wiley Online Library
Chiral aryliodine (III) reagents have provided an advanced concept for enantioselective
synthesis and catalysis. With the advent of chiral iodine (I/III) catalysis, many different …

[PDF][PDF] Hydrogen bonding and alcohol effects in asymmetric hypervalent iodine catalysis: enantioselective oxidative dearomatization of phenols

M Uyanik, T Yasui, K Ishihara - Angew. Chem. Int. Ed, 2013 - academia.edu
The enantioselective oxidative dearomatization of phenols and their analogues is a key
reaction for the synthesis of several natural products.[1] Conventionally, enantioselective …

Promoting intermolecular C–N bond formation under the auspices of iodine (III)

K Muñiz - Accounts of chemical research, 2018 - ACS Publications
Conspectus The quest for the development of new protocols that provide general conditions
for oxidative carbon–nitrogen bond formation has grown over recent years. Within this …

Asymmetric direct/stepwise dearomatization reactions involving hypervalent iodine reagents

R Kumar, FV Singh, N Takenaga… - Chemistry–An Asian …, 2022 - Wiley Online Library
A remarkable growth in hypervalent iodine‐mediated oxidative transformations as
stoichiometric reagents as well as catalysts has been well‐documented due to their …