A selection of perfluoroalkylation reactions of aliphatic substrates that display
methodological and synthetic amplitude will be studied, giving examples of their …

We present a strategy for metal-free, alkene difunctionalization-type, oxy-and amino-
perfluoroalkylations, using perfluoro acid anhydrides as practical and user-friendly …

Recent protocols and reactions for catalytic radical perfluoroalkylations will be described.
The production of perfluoroalkyl radicals (RF= C n F2 n+ 1, n≥ 2), which effect both addition …

This article describes an efficient method for the introduction of perfluoroalkyl groups into N-
acrylamides, 2-isocyanides, olefins, and other heterocycles using perfluoroalkyl radicals that …

An efficient perfluoroalkylation of unactivated alkenes with perfluoro acid anhydrides was
developed. Copper salts play a crucial role as a catalyst to achieve allylic perfluoroalkylation …

Perfluoroalkylation is one of the most important methods for the introduction of multiple
fluorine atoms into organic molecules in a single step. The use of photoinduced technology …

Perfluoroalkyl-containing substances (PFAS), have become omnipresent materials in the
modern world for both commercial and research applications. Compounds such as …

Perfluoroalkylation reactions of arenes have not been the subject of intense study as has
been the case for the trifluoromethylation reactions of aromatics. However, the new synthetic …

We describe a new catalytic approach to selective functionalization of the strong C–F bonds
in trifluoromethylaromatic (Ar–CF3) systems. In this approach, single electron reduction of Ar …

We describe a “ligand-free” Ni-catalyzed perfluoroalkylation of heteroarenes to produce a
diverse array of trfiluoromethyl, pentafluoroethyl and heptafluoropropyl adducts. Catalysis …