Transition-Metal-Free Electrochemical Selenylative Cyclization of Alkynyl Phosphonates
B Li, Y Zhou, Y Xu, X Li, Z Li, L Gu… - The Journal of Organic …, 2023 - ACS Publications
Unprecedented regioselective electrochemical tandem selenation/cyclization of alkynyl
phosphonates with diselenide is described here. These obtained selenoether products can …
phosphonates with diselenide is described here. These obtained selenoether products can …
Electrochemical selenium–π–acid promoted hydration of alkynyl phosphonates
B Li, Y Zhou, Y Sun, F Xiong, L Gu, W Ma… - Chemical …, 2022 - pubs.rsc.org
An unprecedented electrochemical selenium–π–acid promoted hydration of internal alkynes
bearing a phosphonate auxiliary was described. Thus, valuable (hetero) aryl and alkyl …
bearing a phosphonate auxiliary was described. Thus, valuable (hetero) aryl and alkyl …
8π Electrocyclic Reaction of Phosphonate Derivatives: Access to Seven-Membered Cross-Conjugated Cyclic Trienes
H Saito, R Kato, K Ikeuchi, T Suzuki, K Tanino - Organic Letters, 2021 - ACS Publications
An anionic 8π electrocyclic reaction of 4-(diethoxyphosphoryl)-1, 3, 6-heptatriene derivatives
was developed. Under the influence of a base, the substrate underwent deprotonation at the …
was developed. Under the influence of a base, the substrate underwent deprotonation at the …
Selenium-promoted electrophilic cyclization of arylpropiolamides: synthesis of 3-organoselenyl spiro [4, 5] trienones
AMS Recchi, PHP Rosa, DF Back… - Organic & Biomolecular …, 2020 - pubs.rsc.org
This paper describes a selenium-promoted electrophilic cyclization of arylpropiolamides
allowing the synthesis of 3-organoselenyl spiro [4, 5] trienones via a 5-endo-dig ipso-mode …
allowing the synthesis of 3-organoselenyl spiro [4, 5] trienones via a 5-endo-dig ipso-mode …
Electrochemical selenation of phosphonates and phosphine oxides
S Guo, S Li, Z Zhang, W Yan, H Cai - Tetrahedron Letters, 2020 - Elsevier
An environmentally friendly electrocatalytic strategy for the synthesis of
organoselenophospho-rus between phosphonates/phosphine oxides and …
organoselenophospho-rus between phosphonates/phosphine oxides and …
Additive-free, N-chlorosuccinimide-promoted electrophilic phosphorothiolation/cyclization of alkynes with P (O) SH compounds to access heterocyclic …
P Zhang, W Qu, S Yang, L Wang, L Zhang… - Organic Chemistry …, 2024 - pubs.rsc.org
A simple and pratical strategy for the synthesis of phosphorothiolated heterocyclic
compounds from easily prepared alkynes and P (O) SH compounds has been developed …
compounds from easily prepared alkynes and P (O) SH compounds has been developed …
Oxidative cross-coupling between secondary phosphine selenides and thiols or dithiols: a facile regio-selective synthesis of thioselenophosphinic S-esters and S …
NK Gusarova, PA Volkov, NI Ivanova, YV Gatilov… - Tetrahedron …, 2013 - Elsevier
Reactions between secondary phosphine selenides and a wide range of aliphatic, aromatic
and heteroaromatic thiols or dithiols proceed in the Et3N/CCl4 oxidative system under mild …
and heteroaromatic thiols or dithiols proceed in the Et3N/CCl4 oxidative system under mild …
[PDF][PDF] Stereoselective addition of sodium organyl chalcogenolates to alkynylphosphonates: synthesis of diethyl 2-(organyl)-2-(organochalcogenyl) vinylphosphonates
AL Braga, EF Alves, CC Silveira… - Tetrahedron …, 2000 - academia.edu
Organyl thiolate, selenolate or tellurolate anions reacted with alkynylphosphonates 1 to give
diethyl 2-(organyl)-2-(organochalcogenyl) vinylphosphonates [β-organochalcogenyl …
diethyl 2-(organyl)-2-(organochalcogenyl) vinylphosphonates [β-organochalcogenyl …
Visible-light-driven phosphonoalkylation of alkenes
YM Jiang, J Liu, Q Fu, YM Yu, DG Yu - Synlett, 2021 - thieme-connect.com
Phosphonylation of alkenes is important for the generation of valuable organophosphines.
However, redox-neutral difunctionalization of alkenes with readily available HP (O) …
However, redox-neutral difunctionalization of alkenes with readily available HP (O) …
Redox‐Triggered Reversible Interconversion of a Monocyclic and a Bicyclic Phosphorus Heterocycle
D Heift, Z Benkő, H Grützmacher - Angewandte Chemie, 2014 - Wiley Online Library
Molecules which change their structures significantly and reversibly upon an oxidation or
reduction process have potential as future components of smart materials. A prerequisite for …
reduction process have potential as future components of smart materials. A prerequisite for …