Conspectus Transition metal complexes featuring an M═ NR bond have received great
attention as critical intermediates in the synthesis of nitrogen-containing compounds. In …

Iron terminal imido species featuring electron-withdrawing N-substituents represent an
important category of reactive metal-ligand-multiple-bond intermediates in iron-catalyzed …

Iron terminal imido species are typically implicated as reaction intermediates in iron-
catalyzed transformations. While a large body of work has been devoted to mid-and high …

The presence of redox innocent metal ions has been proposed to modulate the reactivity of
metal ligand multiple bonds; however, insight from structure/function relationships is limited …

High-spin, late transition metal imido complexes have attracted significant interest due to
their group transfer reactivity and catalytic C–H activation of organic substrates. Reaction of …

Reduction of previously reported (ArL) FeCl with potassium graphite furnished a low-spin
(S= 1/2) iron complex (ArL) Fe which features an intramolecular η6-arene interaction and …

Dipyrromethene ligand scaffolds were synthesized bearing large aryl (2, 4, 6-Ph3C6H2,
abbreviated Ar) or alkyl (t Bu, adamantyl) flanking groups to afford three new disubstituted …

Reduction of the three-coordinate iron (III) imido [Ph2B (t BuIm) 2Fe═ NDipp](1) affords
[Ph2B (t BuIm) 2Fe═ NDipp][K (18-C-6) THF2](2), a rare example of a high-spin (S= 2) iron …

We present evidence of a spin-state change that accompanies desilylation reactions
performed on two related Fe (II) iminopyridine coordination complexes. To probe these …

Metal imido complexes, generally indicated as L n Mdouble bondNR, are considered key-
intermediates in nitrene transfer reactions, which are efficient and atom-economic …