Mechanistic insights gained by high spatial resolution reactivity mapping of homogeneous and heterogeneous (Electro) catalysts

S Dery, B Friedman, H Shema, E Gross - Chemical Reviews, 2023 - ACS Publications
The recent development of high spatial resolution microscopy and spectroscopy tools
enabled reactivity analysis of homogeneous and heterogeneous (electro) catalysts at …

Looking on heterogeneous catalytic systems from different perspectives: multitechnique approaches as a new challenge for in situ studies

A Brückner - Catalysis Reviews, 2003 - Taylor & Francis
Adapting physico-chemical characterization techniques for in situ studies of real
heterogeneous catalysts during conditioning, reaction, and deactivation processes is a …

Future challenges in heterogeneous catalysis: understanding catalysts under dynamic reaction conditions

KF Kalz, R Kraehnert, M Dvoyashkin… - …, 2017 - Wiley Online Library
Abstract In the future,(electro‐) chemical catalysts will have to be more tolerant towards a
varying supply of energy and raw materials. This is mainly due to the fluctuating nature of …

Evolution and enabling capabilities of spatially resolved techniques for the characterization of heterogeneously catalyzed reactions

K Morgan, J Touitou, JS Choi, C Coney… - ACS …, 2016 - ACS Publications
The development and optimization of catalysts and catalytic processes requires knowledge
of reaction kinetics and mechanisms. In traditional catalyst kinetic characterization, the gas …

In situ and operando electron microscopy in heterogeneous catalysis—insights into multi-scale chemical dynamics

SW Chee, T Lunkenbein, R Schlögl… - Journal of Physics …, 2021 - iopscience.iop.org
This review features state-of-the-art in situ and operando electron microscopy (EM) studies
of heterogeneous catalysts in gas and liquid environments during reaction. Heterogeneous …

Uncovering the Nature of Active Sites during Electrocatalytic Reactions by In Situ Synchrotron-Based Spectroscopic Techniques

L Cao, X Liu, X Shen, D Wu, T Yao - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Catalysts can effectively accelerate the reaction kinetics process and are
recognized as the core to realize the conversion and supply of carbon-free energy …

Introduction to special issue on operando and in situ studies of catalysis

CW Jones, F Tao, MV Garland - ACS Catalysis, 2012 - ACS Publications
This issue features a collection of papers focusing on the emerging area of operando and in
situ studies of catalysis, with a significant emphasis on heterogeneous catalysis …

Operando surface spectroscopy and microscopy during catalytic reactions: from clusters via nanoparticles to meso‐scale aggregates

G Rupprechter - Small, 2021 - Wiley Online Library
Operando characterization of working catalysts, requiring per definitionem the simultaneous
measurement of catalytic performance, is crucial to identify the relevant catalyst structure …

Operando Electron Microscopy of Catalysts: The Missing Cornerstone in Heterogeneous Catalysis Research?

SW Chee, T Lunkenbein, R Schlögl… - Chemical …, 2023 - ACS Publications
Heterogeneous catalysis in thermal gas-phase and electrochemical liquid-phase chemical
conversion plays an important role in our modern energy landscape. However, many of the …

Operando methods: A new era of electrochemistry

Y Yang, J Feijóo, V Briega-Martos, Q Li… - Current Opinion in …, 2023 - Elsevier
One of the grand challenges facing electrochemistry is to directly resolve the complex nature
of (electro) catalyst active sites and capture real-time “movies” of reaction dynamics, ie …