Concise synthesis of deuterium-labelled proanthocyanidin metabolite 5-(3′, 4′-dihydroxyphenyl)-γ-valerolactone as an analytical tool

A Artasensi, S Mazzotta, G Baron, G Aldini… - RSC advances, 2024 - pubs.rsc.org
Deuterated proanthocyanidin metabolite 5-(3′, 4′-dihydroxyphenyl)-γ-valerolactone has
been successfully produced. This metabolite is responsible for several proanthocyanidin …

Developments in extraction, purification, and structural elucidation of proanthocyanidins (2000–2019)

Z Qin, HM Liu, YX Ma, XD Wang - Studies in natural products chemistry, 2021 - Elsevier
Proanthocyanidins (PAs) are polyphenols that are widely distributed in various parts of
plants, eg, fruits, vegetables, nuts, bark, and leaves. PAs can be divided into three classes …

[HTML][HTML] Investigation of oligomeric proanthocyanidins extracted from Rhodiolae Crenulatae Radix et Rhizomes using deep eutectic solvents and identified via data …

L Jia, L Wang, X Zhang, Q Zhang, P Lei… - Journal of …, 2024 - Elsevier
In this study, 34 deep eutectic solvents were successfully prepared for the extraction of
proanthocyanidin from Rhodiolae Crenulatae Radix et Rhizomes. The extraction process …

Stable solid-supported leucoanthocyanidin variants for flavanoid biosynthesis elucidation

D Deffieux, S Gaudrel-Grosay, A Grelard… - Tetrahedron letters, 2009 - Elsevier
Remarkable progress toward the complete elucidation of the biosynthesis of flavanoids has
been accomplished during the last decade, but the final steps presumably involving the …

Unravelling polymeric proanthocyanidin structure via synthesis

D Ferreira, JPJ Marais, VR Adelli - Planta Medica, 2008 - thieme-connect.com
The proanthocyanidin pool of plants is of exceptional complexity. This is mainly due to
extensive variation in hydroxylation pattern as well as several regio-/stereochemical and …

An integrated approach to demonstrating the ANR pathway of proanthocyanidin biosynthesis in plants

QZ Peng, Y Zhu, Z Liu, C Du, KG Li, DY Xie - Planta, 2012 - Springer
Proanthocyanidins (PAs) are oligomers or polymers of plant flavan-3-ols and are important
to plant adaptation in extreme environmental conditions. The characterization of …

Synthesis of (14C)-labeled 5-deoxyflavonoids and their application in the study of dihydroflavonol/leucoanthocyanidin interconversion by dihydroflavonol 4-reductase

H Halbwirth, S Kahl, W Jäger, G Reznicek, G Forkmann… - Plant Science, 2006 - Elsevier
Biosynthesis is well elucidated for 5-hydroxyflavonoids (phloroglucinol type), but for 5-
deoxyflavonoids (resorcinol type) the knowledge is still limited. We provide detailed and …

Functional demonstration of plant flavonoid carbocations proposed to be involved in the biosynthesis of proanthocyanidins.

WPQ Wang PeiQiang, LYJ Liu YaJun… - 2020 - cabidigitallibrary.org
The plant flavonoid dogma proposes that labile plant flavonoid carbocations (PFCs) play
vital roles in the biosynthesis of proanthocyanidins (PAs). However, whether PFCs exist in …

An integrated approach to demonstrating the ANR pathway of proanthocyanidin biosynthesis in plants.

PQZ Peng QingZhong, ZY Zhu Yue, Z Liu, DC Du Ci… - 2012 - cabidigitallibrary.org
Proanthocyanidins (PAs) are oligomers or polymers of plant flavan-3-ols and are important
to plant adaptation in extreme environmental conditions. The characterization of …

Analysis of Proanthocyanidins in Food Ingredients by the 4‐(Dimethylamino) cinnamaldehyde Reaction

D Esquivel‐Alvarado, E Alfaro‐Viquez… - Recent Advances in …, 2023 - Wiley Online Library
Proanthocyanidins (PACs) are oligomeric flavan‐3‐ols found in fruits and botanicals that are
used as ingredients in dietary supplements due to their putative health benefits. In the …