Porous honeycomb self-assembled monolayers: Tripodal adsorption and hidden chirality of carboxylate anchored triptycenes on Ag

S Das, G Nascimbeni, RO De La Morena, F Ishiwari… - ACS …, 2021 - ACS Publications
Molecules with tripodal anchoring to substrates represent a versatile platform for the
fabrication of robust self-assembled monolayers (SAMs), complementing the conventional …

Triptycene tripods for the formation of highly uniform and densely packed self-assembled monolayers with controlled molecular orientation

F Ishiwari, G Nascimbeni, E Sauter… - Journal of the …, 2019 - ACS Publications
When employing self-assembled monolayers (SAMs) for tuning surface and interface
properties, organic molecules that enable strong binding to the substrate, large-area …

N-heterocyclic carbenes for the self-assembly of thin and highly insulating monolayers with high quality and stability

A Krzykawska, M Wróbel, K Kozieł, P Cyganik - ACS nano, 2020 - ACS Publications
As an organic nanostructure, self-assembled monolayers (SAMs) play a central role in many
aspects of nanotechnology, including molecular electronics. In this work, we show that SAMs …

Cyano-substituted triptycene-based monolayers on Au (111): Tripodal adsorption, dipole engineering, and charge transfer

S Das, A Asyuda, Y Shoji, A Kosaka… - The Journal of …, 2021 - ACS Publications
Molecules with tripodal anchoring groups are generally capable of forming self-assembled
monolayers (SAMs), which, however, frequently suffer from inhomogeneous bonding …

Do two-dimensional “noble gas atoms” produce molecular honeycombs at a metal surface?

J Wyrick, DH Kim, D Sun, Z Cheng, W Lu, Y Zhu… - Nano …, 2011 - ACS Publications
Anthraquinone self-assembles on Cu (111) into a giant honeycomb network with exactly
three molecules on each side. Here we propose that the exceptional degree of order …

Triptycene-based self-assembled monolayer as a template for successive click reactions

S Das, F Ishiwari, Y Shoji, T Fukushima… - The Journal of …, 2023 - ACS Publications
Triptycene-based molecules represent a promising platform for tripodal monomolecular
assembly on solid substrates. The versatility of the approach can be increased significantly if …

Chiral self-organized single 2D-layers of tetramers from a functional donor–acceptor molecule by the surface template effect

AJ Kny, M Reimer, N Al-Shamery, R Tomar, T Bredow… - Nanoscale, 2023 - pubs.rsc.org
The ability to control the structural properties of molecular layers is a key for the design and
preparation of organic electronic devices. While microscopic growth studies of planar, rigid …

Asymmetry Induction by Cooperative Intermolecular Hydrogen Bonds in Surface‐Anchored Layers of Achiral Molecules

A Dmitriev, H Spillmann, S Stepanow… - …, 2006 - Wiley Online Library
The mesoscale induction of two‐dimensional supramolecular chirality (formation of 2D
organic domains with a single handedness) was achieved by self‐assembly of 1, 2, 4 …

From Au–thiolate chains to thioether sierpinski triangles: the versatile surface chemistry of 1, 3, 5-Tris (4-mercaptophenyl) benzene on Au (111)

A Rastgoo-Lahrood, N Martsinovich, M Lischka… - Acs Nano, 2016 - ACS Publications
Self-assembly of 1, 3, 5-tris (4-mercaptophenyl) benzene (TMB), a 3-fold symmetric, thiol-
functionalized aromatic molecule, was studied on Au (111) with the aim of realizing …

Nonintuitive surface self-assembly of functionalized molecules on Ag (111)

A Jeindl, J Domke, L Hörmann, F Sojka, R Forker… - ACS …, 2021 - ACS Publications
The fabrication of nanomaterials involves self-ordering processes of functional molecules on
inorganic surfaces. To obtain specific molecular arrangements, a common strategy is to …