The RhII‐catalyzed oxyamination and diamination of alkenes generate 1, 2‐amino alcohols
and 1, 2‐diamines, respectively, in good to excellent yields and with complete regiocontrol …

We report a three-component diamination of simple unactivated alkenes using an
electrophilic nitrene source and amine nucleophiles. The reaction provides rapid access to …

The RhII‐catalyzed intermolecular addition of nitrenes to aromatic and aliphatic alkenes
provides vicinal amino alcohols with yields of up to 95% and complete regioselectivity. This …

The reaction of dienyl carbamates with PhI (OR) 2 in the presence of rhodium catalysts
affords vinyl aziridines which are in situ regio-and stereoselectively opened to afford …

We developed two new catalytic transformations of anilines via oxidative addition of C–N
bonds to ruthenium centers. One is ruthenium-catalyzed reductive deaminatoindeamination …

The intermolecular 1, 3-diamination reaction of readily available alkenes with N-fluorobis (
benzenesulfonamides) catalyzed by rhodium (II) is reported herein. The isomers of the …

Alkenyl N-pivaloylhydroxamates undergo an Ir (III)-catalyzed diamination of the alkene with
simple exogenous secondary amines under extraordinarily mild reaction conditions. The …

The Ir-catalyzed regioselective hydroamination of allyl amines as well as the catalyst-
controlled regiodivergent hydroamination of homoallylic amines with aniline nucleophiles is …

The past few decades have witnessed extensive efforts to disclose the unique reactivity of
metal–nitrenes, because they could be a powerful synthetic tool for introducing the amine …

A RhIII‐catalyzed addition of aryl C H bonds to nitrosobenzenes, followed by cleavage of
the resulting hydroxylamines in situ, has been reported. Different directing groups, such as N …