Unique properties and emerging applications of carbolong metallaaromatics
Conspectus Aromatic compounds are important in synthetic chemistry, biomedicines, and
materials science. As a special type of aromatic complex, transition-metal-based …
materials science. As a special type of aromatic complex, transition-metal-based …
Access to tetracyclic aromatics with bridgehead metals via metalla-click reactions
The never-ending pursuits for exploring aromatic molecular architectures result in the large
libraries of aromatics with fascinating structures, which have greatly broadened the scope of …
libraries of aromatics with fascinating structures, which have greatly broadened the scope of …
A Metal‐Bridged Tricyclic Aromatic System: Synthesis of Osmium Polycyclic Aromatic Complexes
Aromaticity is one of the most important concepts in organic chemistry. A variety of metalla‐
aromatic compounds have been recently prepared and in most of those examples, the metal …
aromatic compounds have been recently prepared and in most of those examples, the metal …
Metallaaromatics Containing Main‐group Heteroatoms
H Wang, X Zhou, H Xia - Chinese Journal of Chemistry, 2018 - Wiley Online Library
Metallaaromatics are metallacycles that are derived from the formal replacement of a carbon
atom in the framework of organic aromatics with a metal fragment. As an important subclass …
atom in the framework of organic aromatics with a metal fragment. As an important subclass …
Metallapentalenofurans and Lactone‐Fused Metallapentalynes
Metalla‐aromatics are attractive species because they exhibit the properties of both
organometallics and aromatics. Reported metal‐bridged polycyclic aromatic complexes, as …
organometallics and aromatics. Reported metal‐bridged polycyclic aromatic complexes, as …
The chemistry of aromatic osmacycles
Aromatic compounds, such as benzene and its derivatives, porphyrins, fullerenes, carbon
nanotubes, and graphene, have numerous applications in biomedicine, materials science …
nanotubes, and graphene, have numerous applications in biomedicine, materials science …
Carbolong chemistry: a story of carbon chain ligands and transition metals
C Zhu, H Xia - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The construction of metal–carbon bonds is one of the most important issues of
organometallic chemistry. However, the chelation of polydentate ligands to a metal via …
organometallic chemistry. However, the chelation of polydentate ligands to a metal via …
Spiro metalla-aromatics of Pd, Pt, and Rh: synthesis and characterization
Since the concept of aromaticity represents one of the most fundamental principles in
chemistry, the search for unprecedented and exciting aromatic systems, therefore, continues …
chemistry, the search for unprecedented and exciting aromatic systems, therefore, continues …
Molecular/polymeric metallaynes and related molecules: Solar cell materials and devices
Energy remains one of the great challenges for the world. There is a considerable interest in
developing renewable energy resources and improving the technologies for energy …
developing renewable energy resources and improving the technologies for energy …
CCCCC pentadentate chelates with planar Möbius aromaticity and unique properties
The coordinating atoms in polydentate chelates are primarily heteroatoms. We present the
first examples of pentadentate chelates with all binding atoms of the chelating agent being …
first examples of pentadentate chelates with all binding atoms of the chelating agent being …