Transition metal-catalyzed oxidative double bond cleavage of simple and bio-derived alkenes and unsaturated fatty acids

P Spannring, PCA Bruijnincx… - Catalysis Science & …, 2014 - pubs.rsc.org
The oxidative cleavage of the CC double bond in unsaturated fatty acids into aldehydes or
carboxylic acids is a reaction of current interest in biomass valorization. The products of this …

Chemically catalyzed oxidative cleavage of unsaturated fatty acids and their derivatives into valuable products for industrial applications: a review and perspective

AE Kerenkan, F Béland, TO Do - Catalysis Science & Technology, 2016 - pubs.rsc.org
Oils and fats of vegetable and animal origin have recently attracted growing interest as
renewable raw materials in oleochemical industries. This attention arises from not only …

Oxidative Cleavage of Alkene C=C Bonds Using a Manganese Catalyzed Oxidation with H2O2 Combined with Periodate Oxidation

F Mecozzi, JJ Dong, D Angelone… - European Journal of …, 2019 - Wiley Online Library
A one‐pot multi‐step method for the oxidative cleavage of alkenes to aldehydes/ketones
under ambient conditions is described as an alternative to ozonolysis. The first step is a …

Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen

T Punniyamurthy, S Velusamy, J Iqbal - Chemical Reviews, 2005 - ACS Publications
Catalytic oxidation is a key technology for converting petroleum-based feedstocks to useful
chemicals of a high oxidation state such as alcohols, carbonyl compounds, and epoxides …

Transition Metal‐Catalyzed Epoxidation of Alkenes

H Adolfsson - Modern Oxidation Methods, 2004 - Wiley Online Library
The formation of epoxides via metal-catalyzed oxidation of alkenes represents the most
elegant and environmentally friendly route for the production of this compound class [1, 2] …

[HTML][HTML] Oxidative cleavage of fatty acid derivatives for monomer synthesis

A Soutelo-Maria, JL Dubois, JL Couturier, G Cravotto - Catalysts, 2018 - mdpi.com
Oxidative cleavage of fatty acids and fatty acid derivatives is a practical way to obtain
bifunctional molecules that can be used in polycondensation reactions. Diacids …

Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst

Z Huang, R Guan, M Shanmugam… - Journal of the …, 2021 - ACS Publications
The oxidative cleavage of C═ C double bonds with molecular oxygen to produce carbonyl
compounds is an important transformation in chemical and pharmaceutical synthesis. In …

Heterogeneous Sodium‐Manganese Oxide Catalyzed Aerobic Oxidative Cleavage of 1, 2‐Diols

V Escande, CH Lam, P Coish… - Angewandte Chemie …, 2017 - Wiley Online Library
The aerobic oxidative cleavage of 1, 2‐diols using a heterogeneous catalyst only based on
earth‐abundant metals manganese and sodium is reported for the first time. This reusable …

Metal-free, NHPI catalyzed oxidative cleavage of C–C double bond using molecular oxygen as oxidant

R Lin, F Chen, N Jiao - Organic letters, 2012 - ACS Publications
A metal-free N-hydroxyphthalimide (NHPI) catalyzed aerobic oxidative cleavage of olefins
has been developed. Molecular oxygen is used as the oxidant and reagent for this …

Fe‐catalyzed one‐pot oxidative cleavage of unsaturated fatty acids into aldehydes with hydrogen peroxide and sodium periodate

P Spannring, V Yazerski, PCA Bruijnincx… - … –a European Journal, 2013 - Wiley Online Library
A one‐pot method has been developed for the oxidative cleavage of internal alkenes into
aldehydes by using 0.5 mol% of the nonheme iron complex [Fe (OTf) 2 (mix‐bpbp)](bpbp …