This report describes the chemoselective coupling of polyfluoroarenes with aryl germanes in
the presence of aromatic C–I, C–Br, C–Cl, C–OTf, and C–SiMe3 groups, as well as …

Gold-catalyzed reactions have witnessed an exponential growth in the past decade. When
the unique modes of activation exhibited by gold species meet species with either …

Despite the unique position of gold catalysis in contemporary organic synthesis, this area of
research is notorious for requiring activators and/or additives that enable catalysis by …

A dual catalytic approach enlisting gold and iron synergy is described. This method offers
readily access to substituted heterocycle aldehydes via oxygen radical addition to vinyl–gold …

An operationally simple and highly selective Au/Ag bimetallic-catalyzed cross-
dehydrogenative biaryl coupling between pyrazoles and fluoroarenes has been developed …

Gold catalysis has witnessed immense evolution in recent years, yet it still requires the use
of activators to render the common [AuCl (L)] complexes catalytically active. Herein, the H …

The reluctance of gold to achieve oxidative addition reaction is considered as an intrinsic
limitation for the development of gold-catalyzed cross-coupling reactions with simple and …

The construction of C–C and C–X (X= hetero atom) bonds is the core aspect for the
assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling …

By adopting the interplay between ligand-enabled Au (I)/Au (III) catalysis and the unique π-
activation mode of gold complexes, a highly coveted 1, 2-heteroarylation of alkenes has …

Transition‐metal‐catalyzed cross‐coupling reactions are central to many organic synthesis
methodologies. Traditionally, Pd, Ni, Cu, and Fe catalysts are used to promote these …