[HTML][HTML] Longitudinal single-sided NMR study: silica-to-alumina ratio changes the reaction mechanism of geopolymer

J Li, S Mailhiot, AM Kantola, H Niu… - Cement and Concrete …, 2022 - Elsevier
Characterizing and understanding the mechanisms underlying geopolymerization are
critical in achieving the use of sustainable construction material, geopolymer, for widespread …

Early-stage geopolymerization revealed by 27Al and 29Si nuclear magnetic resonance spectroscopy based on vacuum dehydration

X Zhu, D Yan, H Fang, S Chen, H Ye - Construction and Building Materials, 2021 - Elsevier
The geopolymerization process affects the mechanical properties and chemical durability of
geopolymer cement by forming alkali aluminosilicate gels of varying degrees of …

A multinuclear static NMR study of geopolymerisation

A Favier, G Habert, N Roussel… - Cement and concrete …, 2015 - Elsevier
Geopolymers are inorganic binders obtained by alkali activation of aluminosilicates. While
the structure of geopolymers is now well understood, the details of the geopolymerisation …

[HTML][HTML] Curing process and pore structure of metakaolin-based geopolymers: Liquid-state 1H NMR investigation

J Li, S Mailhiot, H Sreenivasan, AM Kantola… - Cement and Concrete …, 2021 - Elsevier
Geopolymers are emerging construction materials with lower carbon dioxide emissions
compared to the conventional cementitious materials. The knowledge of the curing process …

Impact of aluminum on the structure of geopolymers from the early stages to consolidated material

V Benavent, P Steins, I Sobrados, J Sanz… - Cement and Concrete …, 2016 - Elsevier
The aim of this study is to assess the effects of the addition of aluminum (NaAlO 2) into the
activating solution on the geopolymerization reactions and the characteristics of the porous …

Low-field 1H NMR study on geopolymers: The effect of paramagnetic Fe (III)

Z Yu, R de Oliveira-Silva, Y Pontikes… - Cement and Concrete …, 2023 - Elsevier
Geopolymers are inorganic polymers with 3D framework structures having superior
mechanical and physical properties. Metakaolin-based geopolymers synthesized using …

Characterization of geopolymers from compositionally and physically different Class F fly ashes

JE Oh, Y Jun, Y Jeong - Cement and Concrete Composites, 2014 - Elsevier
The alkali-activation technology of coal fly ash is one of several potential solutions to
minimize the harmful disposal of fly ash. This study reports high-resolution characterization …

Outstanding problems posed by nonpolymeric particulates in the synthesis of a well-structured geopolymeric material

PS Singh, T Bastow, M Trigg - Cement and Concrete Research, 2004 - Elsevier
In the conventional geopolymer synthesis of ternary reactants system of silicate anions
[Na2O· 2SiO2], metakaolin [Al2O3· 2SiO2] and aqueous alkali [Na2O], the SiO2/Al2O3 molar …

Kinetics of geopolymerization: Role of Al2O3 and SiO2

P De Silva, K Sagoe-Crenstil… - Cement and Concrete …, 2007 - Elsevier
The early-stage reaction kinetics of metakaolin/sodium silicate/sodium hydroxide
geopolymer system have been investigated. The setting and early strength development …

Degree of reaction and phase content of silica-based one-part geopolymers investigated using chemical and NMR spectroscopic methods

P Sturm, S Greiser, GJG Gluth, C Jäger… - Journal of materials …, 2015 - Springer
One-part geopolymers were synthesized from two different silica materials (a silica-rich
residue from chlorosilane production and a commercial microsilica) and sodium aluminate …