A base-resistant metalloporphyrin metal–organic framework for C–H bond halogenation
A base-resistant porphyrin metal–organic framework (MOF), namely PCN-602 has been
constructed with 12-connected [Ni8 (OH) 4 (H2O) 2Pz12](Pz= pyrazolate) cluster and a …
constructed with 12-connected [Ni8 (OH) 4 (H2O) 2Pz12](Pz= pyrazolate) cluster and a …
Construction of ultrastable porphyrin Zr metal–organic frameworks through linker elimination
A series of highly stable MOFs with 3-D nanochannels, namely PCN-224 (no metal, Ni, Co,
Fe), have been assembled with six-connected Zr6 cluster and metalloporphyrins by a linker …
Fe), have been assembled with six-connected Zr6 cluster and metalloporphyrins by a linker …
A stable porphyrin-based porous mog metal–organic framework as an efficient solvent-free catalyst for C–C bond formation
W Jiang, J Yang, YY Liu, SY Song, JF Ma - Inorganic Chemistry, 2017 - ACS Publications
We herein report the porous 4-fold interpenetrated mog (moganite) metal–organic
framework (MOF)[Cd3 (tipp)(bpdc) 2]· DMA· 9H2O (1· Cd; H2tipp= 5, 10, 15, 20-tetrakis (4 …
framework (MOF)[Cd3 (tipp)(bpdc) 2]· DMA· 9H2O (1· Cd; H2tipp= 5, 10, 15, 20-tetrakis (4 …
Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses
J Zheng, M Wu, F Jiang, W Su, M Hong - Chemical Science, 2015 - pubs.rsc.org
Two isostructural porphyrin Zr and Hf metal–organic frameworks (FJI-H6 and FJI-H7) are
rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both …
rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both …
Selective heterogeneous C− H activation/halogenation reactions catalyzed by Pd@ MOF nanocomposites
V Pascanu, F Carson, MV Solano, J Su… - … A European Journal, 2016 - Wiley Online Library
Abstract A directed heterogeneous C− H activation/halogenation reaction catalyzed by
readily synthesized Pd@ MOF nanocatalysts was developed. The heterogeneous Pd …
readily synthesized Pd@ MOF nanocatalysts was developed. The heterogeneous Pd …
Porous metalloporphyrinic frameworks constructed from metal 5, 10, 15, 20-tetrakis (3, 5-biscarboxylphenyl) porphyrin for highly efficient and selective catalytic …
XL Yang, MH Xie, C Zou, Y He, B Chen… - Journal of the …, 2012 - ACS Publications
We incorporate metal 5, 10, 15, 20-tetrakis (3, 5-biscarboxylphenyl) porphyrin (M-H8OCPP),
for the first time, into porous metal–organic frameworks. The self-assembled porous …
for the first time, into porous metal–organic frameworks. The self-assembled porous …
Tailor-made pyrazolide-based metal–organic frameworks for selective catalysis
The predesignable porous structures in metal–organic frameworks (MOFs) render them
quite attractive as a host–guest platform to address a variety of important issues at the …
quite attractive as a host–guest platform to address a variety of important issues at the …
Pyrazolate-based porphyrinic metal–organic framework with extraordinary base-resistance
Guided by a top-down topological analysis, a metal–organic framework (MOF) constructed
by pyrazolate-based porphyrinic ligand, namely, PCN-601, has been rationally designed …
by pyrazolate-based porphyrinic ligand, namely, PCN-601, has been rationally designed …
Porous metal–organic frameworks for heterogeneous biomimetic catalysis
M Zhao, S Ou, CD Wu - Accounts of chemical research, 2014 - ACS Publications
Metalloporphyrins are the active sites in monooxygenases that oxidize a variety of
substrates efficiently and under mild conditions. Researchers have developed artificial …
substrates efficiently and under mild conditions. Researchers have developed artificial …
Manganese catalyzed C–H halogenation
Conspectus The remarkable aliphatic C–H hydroxylations catalyzed by the heme-containing
enzyme, cytochrome P450, have attracted sustained attention for more than four decades …
enzyme, cytochrome P450, have attracted sustained attention for more than four decades …