Rh2(II)-Catalyzed Intermolecular N-Aryl Aziridination of Olefins Using Nonactivated N Atom Precursors

T Deng, W Mazumdar, Y Yoshinaga… - Journal of the …, 2021 - ACS Publications
The development of the first intermolecular Rh2 (II)-catalyzed aziridination of olefins using
anilines as nonactivated N atom precursors and an iodine (III) reagent as the stoichiometric …

Rhodium(II)‐catalyzed aziridinations and CH insertions with [N‐(p‐nitrobenzenesulfonyl)imino]phenyliodinane

P Müller, C Baud, Y Jacquier… - Journal of physical …, 1996 - Wiley Online Library
Abstract The [Rh2 (OAc) 4]‐catalyzed decomposition of NsN (DOUBLE BOND) IPh {[N‐(p‐
nitrobenzenesulfonyl) imino] phenyliodinane} in the presence of olefins affords aziridines in …

A method for rhodium (II)-catalyzed aziridination of olefins

P Müller, C Baud, Y Jacquier - Tetrahedron, 1996 - Elsevier
The [Rh2 (OAc) 4] catalyzed decomposition of (N-(p-nitrobenzenesulfonyl) imino)
phenyliodinane (PhI NNs) in the presence of olefins affords aziridines in yields of 18–85 …

Direct and Stereospecific Synthesis of N‐H and N‐Alkyl Aziridines from Unactivated Olefins Using Hydroxylamine‐O‐Sulfonic Acids

Z Ma, Z Zhou, L Kürti - Angewandte Chemie, 2017 - Wiley Online Library
A RhII‐catalyzed direct and stereospecific N‐H‐and N‐alkyl aziridination of olefins is
reported that uses hydroxylamine‐O‐sulfonic acids as inexpensive, readily available, and …

Rh (II)-catalysed room temperature aziridination of homoallyl-carbamates

CJ Hayes, PW Beavis, LA Humphries - Chemical communications, 2006 - pubs.rsc.org
Rh( ii )-catalysed room temperature aziridination of homoallyl-carbamates - Chemical
Communications (RSC Publishing) DOI:10.1039/B611662K Royal Society of Chemistry View …

[引用][C] Bromine-catalyzed aziridination of olefins. A rare example of atom-transfer redox catalysis by a main group element

JU Jeong, B Tao, I Sagasser, H Henniges… - Journal of the …, 1998 - ACS Publications
Due to their highly regio-and stereoselective ring-opening reactions, aziridines are valued
as building blocks for the synthesis of a wide range of nitrogen-containing compounds. 1 …

Metal-free intramolecular aziridination of alkenes using hypervalent iodine based sulfonyliminoiodanes

RM Moriarty, S Tyagi - Organic Letters, 2010 - ACS Publications
Intramolecular aziridination of alkenyl sulfonyliminoiodanes occurs thermally in the absence
of conventional metal catalysts such as Rh (II) and Cu (II). In rigid molecular systems …

[HTML][HTML] N-Aminopyridinium reagents as traceless activating groups in the synthesis of N-Aryl aziridines

H Tan, S Samanta, A Maity, P Roychowdhury… - Nature …, 2022 - nature.com
N-functionalized aziridines, which are both useful intermediates and important synthetic
targets, can be envisioned as arising from the addition of nitrenes (ie., NR fragments) to …

[PDF][PDF] Hypoiodite‐Mediated Metal‐Free Catalytic Aziridination of Alkenes

A Yoshimura, KR Middleton, C Zhu… - Angewandte Chemie …, 2012 - academia.edu
Aziridination of alkenes is an important chemical transformation and is a convenient method
for accessing various nitrogen-containing products and synthetic intermediates.[1] …

Direct N-H/N-Me Aziridination of Unactivated Olefins Using O-(Sulfonyl)hydroxylamines as Aminating Agents

S Sabir, CB Pandey, AK Yadav, B Tiwari… - The Journal of Organic …, 2018 - ACS Publications
Unactivated aziridines are the core substructures in a plethora of bioactive natural products
and serve as building blocks in organic synthesis. Despite this, very limited methods are …