Structural origin of enhanced slow dynamics near a wall in glass-forming systems

K Watanabe, T Kawasaki, H Tanaka - Nature materials, 2011 - nature.com
Spatial confinement is known to induce a drastic change in the viscosity, relaxation times,
and flow profile of liquids near the glass (or jamming) transition point. The essential …

Direct evidence of void-induced structural relaxations in colloidal glass formers

CT Yip, M Isobe, CH Chan, S Ren, KP Wong, Q Huo… - Physical review …, 2020 - APS
Particle dynamics in supercooled liquids are often dominated by stringlike motions in which
lines of particles perform activated hops cooperatively. The structural features triggering …

Structures and dynamics of glass-forming colloidal liquids under spherical confinement

B Zhang, X Cheng - Physical review letters, 2016 - APS
Recent theories predict that when a supercooled liquid approaches the glass transition,
particle clusters with a special “amorphous order” nucleate within the liquid, which lead to …

Multiple reentrant glass transitions in confined hard-sphere glasses

S Mandal, S Lang, M Gross, M Oettel, D Raabe… - Nature …, 2014 - nature.com
Glass-forming liquids exhibit a rich phenomenology upon confinement. This is often related
to the effects arising from wall–fluid interactions. Here we focus on the interesting limit where …

Cage size and jump precursors in glass-forming liquids: experiment and simulations

R Pastore, G Pesce, A Sasso… - The Journal of Physical …, 2017 - ACS Publications
Glassy dynamics is intermittent, as particles suddenly jump out of the cage formed by their
neighbors, and heterogeneous, as these jumps are not uniformly distributed across the …

Influence of polydispersity on the relaxation mechanisms of glassy liquids

I Pihlajamaa, CCL Laudicina, LMC Janssen - Physical Review Research, 2023 - APS
State-of-the-art techniques for simulating deeply supercooled liquids require a high degree
of size polydispersity to be effective. While these techniques have enabled great insight into …

Similarity of wet granular packing to gels

J Li, Y Cao, C Xia, B Kou, X Xiao, K Fezzaa… - Nature …, 2014 - nature.com
To date, there is still no general consensus on the fundamental principle that governs glass
transition. Colloidal suspensions are ordinarily utilized as model systems to study the …

Comparison of dynamical heterogeneity in hard-sphere and attractive glass formers

DR Reichman, E Rabani… - The Journal of Physical …, 2005 - ACS Publications
Using molecular dynamics simulations, we have determined that the nature of dynamical
heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly …

Scaling between structural relaxation and particle caging in a model colloidal gel

C De Michele, E Del Gado, D Leporini - Soft Matter, 2011 - pubs.rsc.org
In glassy dynamics, the rattling of particles in a cage formed by their neighbors is typically
limited to a length scale of the order of the particle diameter but is nevertheless strongly …

Tetrahedrality dictates dynamics in hard sphere mixtures

S Marín-Aguilar, HH Wensink, G Foffi, F Smallenburg - Physical Review Letters, 2020 - APS
The link between local structure and dynamical slowdown in glassy fluids has been the
focus of intense debate for the better part of a century. Nonetheless, a simple method to …