Structural origin of enhanced slow dynamics near a wall in glass-forming systems
K Watanabe, T Kawasaki, H Tanaka - Nature materials, 2011 - nature.com
Spatial confinement is known to induce a drastic change in the viscosity, relaxation times,
and flow profile of liquids near the glass (or jamming) transition point. The essential …
and flow profile of liquids near the glass (or jamming) transition point. The essential …
Direct evidence of void-induced structural relaxations in colloidal glass formers
Particle dynamics in supercooled liquids are often dominated by stringlike motions in which
lines of particles perform activated hops cooperatively. The structural features triggering …
lines of particles perform activated hops cooperatively. The structural features triggering …
Structures and dynamics of glass-forming colloidal liquids under spherical confinement
Recent theories predict that when a supercooled liquid approaches the glass transition,
particle clusters with a special “amorphous order” nucleate within the liquid, which lead to …
particle clusters with a special “amorphous order” nucleate within the liquid, which lead to …
Multiple reentrant glass transitions in confined hard-sphere glasses
Glass-forming liquids exhibit a rich phenomenology upon confinement. This is often related
to the effects arising from wall–fluid interactions. Here we focus on the interesting limit where …
to the effects arising from wall–fluid interactions. Here we focus on the interesting limit where …
Cage size and jump precursors in glass-forming liquids: experiment and simulations
Glassy dynamics is intermittent, as particles suddenly jump out of the cage formed by their
neighbors, and heterogeneous, as these jumps are not uniformly distributed across the …
neighbors, and heterogeneous, as these jumps are not uniformly distributed across the …
Influence of polydispersity on the relaxation mechanisms of glassy liquids
State-of-the-art techniques for simulating deeply supercooled liquids require a high degree
of size polydispersity to be effective. While these techniques have enabled great insight into …
of size polydispersity to be effective. While these techniques have enabled great insight into …
Similarity of wet granular packing to gels
To date, there is still no general consensus on the fundamental principle that governs glass
transition. Colloidal suspensions are ordinarily utilized as model systems to study the …
transition. Colloidal suspensions are ordinarily utilized as model systems to study the …
Comparison of dynamical heterogeneity in hard-sphere and attractive glass formers
DR Reichman, E Rabani… - The Journal of Physical …, 2005 - ACS Publications
Using molecular dynamics simulations, we have determined that the nature of dynamical
heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly …
heterogeneity in jammed liquids is very sensitive to short-ranged attractions. Weakly …
Scaling between structural relaxation and particle caging in a model colloidal gel
In glassy dynamics, the rattling of particles in a cage formed by their neighbors is typically
limited to a length scale of the order of the particle diameter but is nevertheless strongly …
limited to a length scale of the order of the particle diameter but is nevertheless strongly …
Tetrahedrality dictates dynamics in hard sphere mixtures
The link between local structure and dynamical slowdown in glassy fluids has been the
focus of intense debate for the better part of a century. Nonetheless, a simple method to …
focus of intense debate for the better part of a century. Nonetheless, a simple method to …