Single-crystalline imine-linked two-dimensional covalent organic frameworks separate benzene and cyclohexane efficiently

A Natraj, W Ji, J Xin, I Castano, DW Burke… - Journal of the …, 2022 - ACS Publications
Two-dimensional (2D) covalent organic frameworks (COFs) are composed of structurally
precise, permanently porous, layered macromolecular sheets, which are traditionally …

New mechanistic insights into the formation of imine-linked two-dimensional covalent organic frameworks

C Feriante, AM Evans, S Jhulki, I Castano… - Journal of the …, 2020 - ACS Publications
A more robust mechanistic understanding of imine-linked two-dimensional covalent organic
frameworks (2D COFs) is needed to improve their crystalline domain sizes and to control …

Tuning crystallinity and stacking of two-dimensional covalent organic frameworks through side-chain interactions

CE Pelkowski, A Natraj, CD Malliakas… - Journal of the …, 2023 - ACS Publications
Two-dimensional covalent organic frameworks (2D COFs) form as layered 2D polymers
whose sheets stack through high-surface-area, noncovalent interactions that can give rise to …

Single-crystal three-dimensional covalent organic framework constructed from 6-connected triangular prism node

Y Yin, Y Zhang, X Zhou, B Gui, G Cai… - Journal of the …, 2023 - ACS Publications
The limited structural diversity of three-dimensional covalent organic frameworks (3D COFs)
greatly restricts their application exploration. Therefore, there is an urgent need to expand …

Two-dimensional covalent organic framework solid solutions

RL Li, A Yang, NC Flanders, MT Yeung… - Journal of the …, 2021 - ACS Publications
Covalent organic frameworks (COFs) generally leverage one or two monomers with specific
sizes and shapes to access highly symmetric and periodic polymer networks. Almost all …

Substoichiometric 3D covalent organic frameworks based on hexagonal linkers

L Chen, C Gong, X Wang, F Dai, M Huang… - Journal of the …, 2021 - ACS Publications
Covalent organic frameworks (COFs), a fast-growing field in crystalline porous materials,
have achieved tremendous success in structure development and application exploration …

Reticulating 1D ribbons into 2D covalent organic frameworks by imine and imide linkages

HL Nguyen, C Gropp, OM Yaghi - Journal of the American …, 2020 - ACS Publications
The design and synthesis of 2D and 3D crystalline covalent organic frameworks (COFs) from
macromolecular and even infinite building units is largely undeveloped. Here, we report a …

3D covalent organic frameworks selectively crystallized through conformational design

HL Nguyen, C Gropp, Y Ma, C Zhu… - Journal of the American …, 2020 - ACS Publications
We present a strategy whereby selective formation of imine covalent organic frameworks
(COFs) based on linking of triangles and squares into the fjh topology was achieved by the …

Constructing a 3D covalent organic framework from 2D hcb nets through inclined interpenetration

Y Xiao, Y Ling, K Wang, S Ren, Y Ma… - Journal of the American …, 2023 - ACS Publications
Three-dimensional covalent organic frameworks (3D COFs) have been of great interest due
to their inherent numerous open sites and pore confinement effect. However, it has …

Rapid Synthesis of High Surface Area Imine‐Linked 2D Covalent Organic Frameworks by Avoiding Pore Collapse During Isolation

CH Feriante, S Jhulki, AM Evans, RR Dasari… - Advanced …, 2020 - Wiley Online Library
Imine‐linked 2D covalent organic frameworks (COFs) form more rapidly than previously
reported under Brønsted acid‐catalyzed conditions, showing signs of crystallinity within a …