Single-crystalline imine-linked two-dimensional covalent organic frameworks separate benzene and cyclohexane efficiently
Two-dimensional (2D) covalent organic frameworks (COFs) are composed of structurally
precise, permanently porous, layered macromolecular sheets, which are traditionally …
precise, permanently porous, layered macromolecular sheets, which are traditionally …
New mechanistic insights into the formation of imine-linked two-dimensional covalent organic frameworks
A more robust mechanistic understanding of imine-linked two-dimensional covalent organic
frameworks (2D COFs) is needed to improve their crystalline domain sizes and to control …
frameworks (2D COFs) is needed to improve their crystalline domain sizes and to control …
Tuning crystallinity and stacking of two-dimensional covalent organic frameworks through side-chain interactions
CE Pelkowski, A Natraj, CD Malliakas… - Journal of the …, 2023 - ACS Publications
Two-dimensional covalent organic frameworks (2D COFs) form as layered 2D polymers
whose sheets stack through high-surface-area, noncovalent interactions that can give rise to …
whose sheets stack through high-surface-area, noncovalent interactions that can give rise to …
Single-crystal three-dimensional covalent organic framework constructed from 6-connected triangular prism node
Y Yin, Y Zhang, X Zhou, B Gui, G Cai… - Journal of the …, 2023 - ACS Publications
The limited structural diversity of three-dimensional covalent organic frameworks (3D COFs)
greatly restricts their application exploration. Therefore, there is an urgent need to expand …
greatly restricts their application exploration. Therefore, there is an urgent need to expand …
Two-dimensional covalent organic framework solid solutions
Covalent organic frameworks (COFs) generally leverage one or two monomers with specific
sizes and shapes to access highly symmetric and periodic polymer networks. Almost all …
sizes and shapes to access highly symmetric and periodic polymer networks. Almost all …
Substoichiometric 3D covalent organic frameworks based on hexagonal linkers
L Chen, C Gong, X Wang, F Dai, M Huang… - Journal of the …, 2021 - ACS Publications
Covalent organic frameworks (COFs), a fast-growing field in crystalline porous materials,
have achieved tremendous success in structure development and application exploration …
have achieved tremendous success in structure development and application exploration …
Reticulating 1D ribbons into 2D covalent organic frameworks by imine and imide linkages
The design and synthesis of 2D and 3D crystalline covalent organic frameworks (COFs) from
macromolecular and even infinite building units is largely undeveloped. Here, we report a …
macromolecular and even infinite building units is largely undeveloped. Here, we report a …
3D covalent organic frameworks selectively crystallized through conformational design
We present a strategy whereby selective formation of imine covalent organic frameworks
(COFs) based on linking of triangles and squares into the fjh topology was achieved by the …
(COFs) based on linking of triangles and squares into the fjh topology was achieved by the …
Constructing a 3D covalent organic framework from 2D hcb nets through inclined interpenetration
Three-dimensional covalent organic frameworks (3D COFs) have been of great interest due
to their inherent numerous open sites and pore confinement effect. However, it has …
to their inherent numerous open sites and pore confinement effect. However, it has …
Rapid Synthesis of High Surface Area Imine‐Linked 2D Covalent Organic Frameworks by Avoiding Pore Collapse During Isolation
Imine‐linked 2D covalent organic frameworks (COFs) form more rapidly than previously
reported under Brønsted acid‐catalyzed conditions, showing signs of crystallinity within a …
reported under Brønsted acid‐catalyzed conditions, showing signs of crystallinity within a …