Exciton-phonon coupling in the ultraviolet absorption and emission spectra of bulk hexagonal boron nitride

F Paleari, H PC Miranda, A Molina-Sánchez, L Wirtz - Physical review letters, 2019 - APS
We present an ab initio method to calculate phonon-assisted absorption and emission
spectra in the presence of strong excitonic effects. We apply the method to bulk hexagonal …

First-principles study of luminescence in hexagonal boron nitride single layer: Exciton-phonon coupling and the role of substrate

P Lechifflart, F Paleari, D Sangalli, C Attaccalite - Physical Review Materials, 2023 - APS
Hexagonal boron nitride (hBN) is a wide band gap material with both strong excitonic light
emission in the ultraviolet and strong exciton-phonon coupling. Luminescence experiments …

Theory of phonon-assisted luminescence in solids: application to hexagonal boron nitride

E Cannuccia, B Monserrat, C Attaccalite - Physical Review B, 2019 - APS
We study the luminescence of hexagonal boron nitride (h-BN) by means of nonequilibrium
Green's functions plus finite-difference electron-phonon coupling. We derive a formula for …

Phonon-assisted emission and absorption of individual color centers in hexagonal boron nitride

D Wigger, R Schmidt, O Del Pozo-Zamudio… - 2D …, 2019 - iopscience.iop.org
Defect centers in hexagonal boron nitride represent room-temperature single-photon
sources in a layered van der Waals material. These light emitters appear with a wide range …

Exciton interference in hexagonal boron nitride

L Sponza, H Amara, F Ducastelle, A Loiseau… - Physical Review B, 2018 - APS
In this letter we report a thorough analysis of the exciton dispersion in bulk hexagonal boron
nitride. We solve the ab initio GW Bethe-Salpeter equation at finite q∥ Γ K, which is relevant …

Bright luminescence from indirect and strongly bound excitons in h-BN

L Schué, L Sponza, A Plaud, H Bensalah, K Watanabe… - Physical review …, 2019 - APS
A quantitative analysis of the excitonic luminescence efficiency in hexagonal boron nitride (h-
BN) is carried out by cathodoluminescence in the ultraviolet range and compared with zinc …

Overtones of interlayer shear modes in the phonon-assisted emission spectrum of hexagonal boron nitride

TQP Vuong, G Cassabois, P Valvin, V Jacques… - Physical review B, 2017 - APS
We address the intrinsic optical properties of hexagonal boron nitride in deep ultraviolet. We
show that the fine structure of the phonon replicas arises from overtones involving up to six …

Combining experiments on luminescent centres in hexagonal boron nitride with the polaron model and ab initio methods towards the identification of their microscopic …

M Fischer, A Sajid, J Iles-Smith, A Hötger, DI Miakota… - Nanoscale, 2023 - pubs.rsc.org
The two-dimensional material hexagonal boron nitride (hBN) hosts luminescent centres with
emission energies of∼ 2 eV which exhibit pronounced phonon sidebands. We investigate …

Phonon sidebands of color centers in hexagonal boron nitride

P Khatri, IJ Luxmoore, AJ Ramsay - Physical Review B, 2019 - APS
Low temperature photoluminescence spectra of the phonon sidebands of a color center in
hexagonal boron nitride are compared to an independent boson model. We infer that the LA …

Distinguishing different stackings in layered materials via luminescence spectroscopy

M Zanfrognini, A Plaud, I Stenger, F Fossard… - Physical Review Letters, 2023 - APS
Despite its simple crystal structure, layered boron nitride features a surprisingly complex
variety of phonon-assisted luminescence peaks. We present a combined experimental and …