[HTML][HTML] Growth kinetics of the adsorbed layer of poly (2-vinylpyridine)–an indirect observation of desorption of polymers from substrates

M Gawek, H Omar, P Szymoniak, A Schönhals - Soft matter, 2023 - pubs.rsc.org
The growth kinetics of the adsorbed layer of poly (2-vinylpiridine) on silicon oxide is studied
using a leaching technique which is based on the Guiselin brushes approach. The adsorbed …

Adsorption and Dynamics of Low Molecular Weight Poly(styrene-b-2-vinylpyridine) on Silica and Alumina in Toluene

M Xie, FD Blum - Langmuir, 1996 - ACS Publications
Low molecular weight (ca. 10 000 g/mol) specifically-labeled block copolymers of poly (β-
deuterostyrene-b-2-vinylpyridine)(β-DSVP) have been prepared by anionic polymerization …

In situ thickness determination of adsorbed layers of poly (2-vinylpyridine)− polystyrene diblock copolymers by ellipsometry

R Toomey, J Mays, M Tirrell - Macromolecules, 2004 - ACS Publications
To gain more insight into the process of formation of adsorbed layers of diblock copolymers,
ellipsometry was used to monitor in situ the thickness and adsorbed amount of a series of …

[HTML][HTML] Solid-state polymer adsorption for surface modification: The role of molecular weight

W Xu, K Mihhels, N Kotov, S Lepikko, RHA Ras… - Journal of Colloid and …, 2022 - Elsevier
Hypothesis Solid-state polymer adsorption offers a distinct approach for surface
modification. These ultrathin, so-called Guiselin layers can easily be obtained by placing a …

Diffusion-controlled growth of aggregates in layer-by-layer films of poly (o-methoxyaniline)

NC De Souza, JR Silva, CA Rodrigues, AC Hernandes… - 2003 - repositorio.unesp.br
The adsorption process in layer-by-layer (LBL) films of poly (o-methoxyaniline) alternated
with poly (vinyl sulfonic acid) is explained using the Avrami equation. This equation was …

Layered structure in the crystalline adsorption layer and the leaching process of poly (vinyl alcohol) revealed by neutron reflectivity

T Miyazaki, N Miyata, H Arima-Osonoi, H Kira… - Langmuir, 2021 - ACS Publications
We investigated the structure of the crystalline adsorption layer of poly (vinyl alcohol)(PVA)
in hot water by neutron reflectivity in two cases: when the adsorption layer is exposed on the …

Orientation effects for quaternized poly-4-vinylpyridine adsorption onto an oxidized silicon surface

KS Schmitz - Macromolecules, 2000 - ACS Publications
Adsorption of ligands onto surfaces is an active area of study in many fields. Of interest in the
present paper is the study by Sukhishvili and Granick1 on the adsorption of the quaternized …

Adsorption of poly (vinyl alcohol) from water to a hydrophobic surface: effects of molecular weight, degree of hydrolysis, salt, and temperature

M Kozlov, TJ McCarthy - Langmuir, 2004 - ACS Publications
The adsorption of poly (vinyl alcohol)(PVOH) from aqueous solutions to a silicon-supported
fluoroalkyl monolayer is described. Thickness, wettability, and roughness of adsorbed films …

Forces between two poly (2-vinylpyridine)-covered surfaces as a function of ionic strength and polymer charge

J Marra, ML Hair - The Journal of Physical Chemistry, 1988 - ACS Publications
A report is given of the direct measurement of surface forces between two poly (2-
vinylpyridine)(P2VP)-covered mica surfaces both in acid solutions (where P2VP is fully …

Do interfacial layers in thin films act as an independent layer within thin films?

S Madkour, M Gawek, A Hertwig… - Macromolecules, 2020 - ACS Publications
The thermodynamic behavior of thin Poly (vinyl methyl ether)(PVME) films including the
irreversible adsorbed layer on the substrate is investigated. In the first step, the growth …