[HTML][HTML] Unimolecular decay strongly limits the atmospheric impact of Criegee intermediates
Stabilized Criegee intermediates (SCI) are reactive oxygenated species formed in the
ozonolysis of hydrocarbons. Their chemistry could influence the oxidative capacity of the …
ozonolysis of hydrocarbons. Their chemistry could influence the oxidative capacity of the …
Unimolecular decay dynamics of Criegee intermediates: Energy-resolved rates, thermal rates, and their atmospheric impact
TA Stephenson, MI Lester - International Reviews in Physical …, 2020 - Taylor & Francis
Criegee intermediates are reactive species formed in the ozonolysis of alkenes. Their
subsequent chemistry is critical to an accounting of OH production, aerosol formation, and …
subsequent chemistry is critical to an accounting of OH production, aerosol formation, and …
Atmospheric chemistry of Criegee intermediates: Unimolecular reactions and reactions with water
Criegee intermediates are produced in the ozonolysis of unsaturated hydrocarbons in the
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
troposphere, and understanding their fate is a prerequisite to modeling climate-controlling …
The physical chemistry of Criegee intermediates in the gas phase
DL Osborn, CA Taatjes - International Reviews in Physical …, 2015 - Taylor & Francis
Carbonyl oxides, also known as Criegee intermediates, are key intermediates in both gas
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
phase ozonolysis of unsaturated hydrocarbons in the troposphere and solution phase …
Chemically activated formation of organic acids in reactions of the Criegee intermediate with aldehydes and ketones
Reactions of the Criegee intermediate (CI,˙ CH2OO˙) are important in atmospheric
ozonolysis models. In this work, we compute the rates for reactions between˙ CH2OO˙ and …
ozonolysis models. In this work, we compute the rates for reactions between˙ CH2OO˙ and …
Criegee intermediates: production, detection and reactivity
In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
biradical/zwitterionic character (R1R2COO) that form during the ozonolysis of alkenes. First …
The reaction of Criegee intermediates with NO, RO 2, and SO 2, and their fate in the atmosphere
L Vereecken, H Harder, A Novelli - Physical Chemistry Chemical …, 2012 - pubs.rsc.org
The reaction of Criegee intermediates (CI) with NO and RO2 radicals is studied for the first
time by theoretical methodologies; additionally, the reaction of CI with SO2 molecules is re …
time by theoretical methodologies; additionally, the reaction of CI with SO2 molecules is re …
Criegee intermediates: What direct production and detection can teach us about reactions of carbonyl oxides
CA Taatjes - Annual Review of Physical Chemistry, 2017 - annualreviews.org
The carbonyl oxide intermediates in the ozonolysis of alkenes, often known as Criegee
intermediates, are potentially important reactants in Earth's atmosphere. For decades …
intermediates, are potentially important reactants in Earth's atmosphere. For decades …
Research frontiers in the chemistry of Criegee intermediates and tropospheric ozonolysis
The chemistry of carbonyl oxides, known as Criegee intermediates, is central to many
aspects of tropospheric chemistry. For decades it has been known that these reactive …
aspects of tropospheric chemistry. For decades it has been known that these reactive …
[HTML][HTML] Rapid unimolecular reaction of stabilized Criegee intermediates and implications for atmospheric chemistry
Elucidating atmospheric oxidation mechanisms is necessary for estimating the lifetimes of
atmospheric species and understanding secondary organic aerosol formation and …
atmospheric species and understanding secondary organic aerosol formation and …
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