Isotopic constraints on biogeochemical cycling of Fe

CM Johnson, BL Beard, EE Roden… - … in mineralogy and …, 2004 - pubs.geoscienceworld.org
Cycling of redox-sensitive elements such as Fe is affected by not only ambient EhpH
conditions, but also by a significant biomass that may derive energy through changes in …

Iron isotope fractionation during microbially stimulated Fe (II) oxidation and Fe (III) precipitation

N Balci, TD Bullen, K Witte-Lien, WC Shanks… - … et Cosmochimica Acta, 2006 - Elsevier
Interpretation of the origins of iron-bearing minerals preserved in modern and ancient rocks
based on measured iron isotope ratios depends on our ability to distinguish between …

The iron isotope fingerprints of redox and biogeochemical cycling in modern and ancient Earth

CM Johnson, BL Beard… - Annu. Rev. Earth Planet …, 2008 - annualreviews.org
The largest Fe isotope fractionations occur during redox changes, as well as differences in
bonding, but these are expressed only in natural environments in which significant …

Iron isotope fractionation by Fe (II)-oxidizing photoautotrophic bacteria

LR Croal, CM Johnson, BL Beard… - … et cosmochimica acta, 2004 - Elsevier
Photoautotrophic bacteria that oxidize ferrous iron (Fe [II]) under anaerobic conditions are
thought to be ancient in origin, and the ferric (hydr) oxide mineral products of their …

Microbial production of isotopically light iron (II) in a modern chemically precipitated sediment and implications for isotopic variations in ancient rocks

GE Tangalos, BL Beard, CM Johnson, CN Alpers… - …, 2010 - Wiley Online Library
The inventories and Fe isotope composition of aqueous Fe (II) and solid‐phase Fe
compounds were quantified in neutral‐pH, chemically precipitated sediments downstream of …

Evidence for equilibrium iron isotope fractionation by nitrate-reducing iron (II)-oxidizing bacteria

A Kappler, CM Johnson, HA Crosby, BL Beard… - … et cosmochimica acta, 2010 - Elsevier
Iron isotope fractionations produced during chemical and biological Fe (II) oxidation are
sensitive to the proportions and nature of dissolved and solid-phase Fe species present, as …

[图书][B] Iron geochemistry: an isotopic perspective

C Johnson, B Beard, S Weyer - 2020 - Springer
Iron is a remarkable element in its relatively high abundance for its mass and its sensitivity to
(and control of) redox on a planetary scale over geologic time. Numerous volumes have …

Fractionation of Fe isotopes during Fe (II) oxidation by a marine photoferrotroph is controlled by the formation of organic Fe-complexes and colloidal Fe fractions

ED Swanner, W Wu, R Schoenberg, J Byrne… - … et Cosmochimica Acta, 2015 - Elsevier
Much interest exists in finding mineralogical, organic, morphological, or isotopic
biosignatures for Fe (II)-oxidizing bacteria (FeOB) that are retained in Fe-rich sediments …

Demonstration of significant abiotic iron isotope fractionation in nature

TD Bullen, AF White, CW Childs, DV Vivit… - …, 2001 - pubs.geoscienceworld.org
Field and laboratory studies reveal that the mineral ferrihydrite, formed as a result of abiotic
oxidation of aqueous ferrous to ferric Fe, contains Fe that is isotopically heavy relative to …

The global iron cycle

B Kendall, AD Anbar, A Kappler… - Fundamentals of …, 2012 - Wiley Online Library
Iron is a redox-sensitive element. It forms poorly soluble iron oxyhydroxides in the presence
of O2, poorly soluble iron sulfides in the presence of dissolved sulfide, but soluble Fe (II) …