Isolation of cyclic (alkyl) amino carbenes (cAACs) in 2005 has been a major achievement in
the field of stable carbenes due to their better electronic properties. cAACs and bicyclic …

The first synthesis of cyclic (alkyl)(amino) carbenes (cAACs) was reported in 2005, and since
then this class of carbenes has been on a victory tour in main‐group‐element and transition …

Abstract Discovered in 2005, cyclic (alkyl)(amino) carbenes (CAACs) are among the most
nucleophilic (σ donating) and also electrophilic (π‐accepting) stable carbenes known to …

A straightforward strategy allows for the synthesis of storable bicyclic (alkyl)(amino)
carbenes (BICAACs), which feature enhanced σ-donating and π-accepting properties …

Conspectus Carbenes are compounds that feature a divalent carbon atom with only six
electrons in its valence shell. In the singlet state, they possess a lone pair of electrons and a …

The isolation of cyclic (alkyl)(amino) carbenes (CAACs) and N, N′‐diamidocarbenes
(DACs) has opened up new avenues in the field of carbene chemistry due to their unique …

The success of homogeneous catalysis can be attributed largely to the development of a
diverse range of ligand frameworks that have been used to tune the behavior of various …

The availability of catalysts to perform specific transformations is critical for both industry and
academia. Over the years, the success of homogeneous catalysis can be attributed largely …

N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …

Acyclic aminocarbenes have received much less attention as ancillary ligands in
homogeneous catalysis compared with their cyclic relatives (ie, N-heterocyclic carbenes …