Molecular-level understanding of metal ion retention in clay-rich materials

X Liu, C Tournassat, S Grangeon… - Nature Reviews Earth & …, 2022 - nature.com
Clay minerals retain or adsorb metal ions in the Earth's critical zone. Rocks, sediments and
soils rich in clay minerals can concentrate rare earth elements (REEs) in ion adsorption-type …

Adsorption and removal of metal ions by smectites nanoparticles: Mechanistic aspects, and impacts of charge location and edge structure

X Liu, S Yang, P Gu, S Liu, G Yang - Applied Clay Science, 2021 - Elsevier
Clay minerals are efficient adsorbents for metal ions and have been widely used to control
heavy metals, while a number of critical issues remain elusive. In this study, the fully flexible …

Ion adsorption and diffusion in smectite: Molecular, pore, and continuum scale views

RM Tinnacher, M Holmboe, C Tournassat… - … et Cosmochimica Acta, 2016 - Elsevier
Clay-rich media have been proposed as engineered barrier materials or host rocks for high
level radioactive waste repositories in several countries. Hence, a detailed understanding of …

Zinc adsorption on clays inferred from atomistic simulations and EXAFS spectroscopy

SV Churakov, R Dähn - Environmental science & technology, 2012 - ACS Publications
Clay minerals are efficient sinks for heavy metals in the geosphere. Knowing the uptake
mechanism of these elements on clays can help to protect the natural environment from …

Surface complexation of heavy metal cations on clay edges: insights from first principles molecular dynamics simulation of Ni (II)

C Zhang, X Liu, X Lu, M He, EJ Meijer… - … et Cosmochimica Acta, 2017 - Elsevier
Aiming at an atomistic mechanism of heavy metal cation complexing on clay surfaces, we
carried out systematic first principles molecular dynamics (FPMD) simulations to investigate …

[PDF][PDF] Modeling specific pH dependent sorption of divalent metals on montmorillonite surfaces. A review of pitfalls, recent achievements and current challenges

C Tournassat, S Grangeon, P Leroy… - American Journal of …, 2013 - ajsonline.org
Within the context of the clay barrier concept for underground nuclear waste disposal,
montmorillonite and bentonite have been widely used as reference materials for sorption. In …

Differential adsorption of clay minerals: Implications for organic matter enrichment

T Zhao, S Xu, F Hao - Earth-Science Reviews, 2023 - Elsevier
The interactions between clay minerals and organic matter, specifically adsorption, are
widely recognized as a crucial mechanism for promoting the preservation of organic matter …

The link between clay mineral weathering and the stabilization of Ni surface precipitates

RG Ford, AC Scheinost, KG Scheckel… - … science & technology, 1999 - ACS Publications
The formation of transition-metal surface precipitates may occur during sorption to clay
minerals under ambient soil conditions. This process may lead to significant long-term …

Adsorption of rare earth elements in regolith-hosted clay deposits

AM Borst, MP Smith, AA Finch, G Estrade… - Nature …, 2020 - nature.com
Global resources of heavy Rare Earth Elements (REE) are dominantly sourced from
Chinese regolith-hosted ion-adsorption deposits in which the REE are inferred to be weakly …

Selective adsorption and irreversible fixation behavior of cesium onto 2: 1 layered clay mineral: A mini review

SM Park, DS Alessi, K Baek - Journal of hazardous materials, 2019 - Elsevier
In this study, we reviewed the selective adsorption and irreversible fixation of cesium (Cs+)
on clay minerals. The selective adsorption of Cs+ results from reactions with frayed edge …