A total synthesis of the ingenane-derived diterpenoid (+)-euphorikanin A is described. Key to
the strategy is a stereocontrolled one-pot sequence consisting of transannular aldol addition …

We disclose the first total synthesis of (+)-euphorikanin A, an ingenane-derived natural
product featuring an unprecedented 5/6/7/3-fused tetracyclic skeleton. Key to the approach …

Euphorikanin A is a diterpenoid possessing a highly congested and unprecedented 5/6/7/3-
fused tetracyclic ring skeleton. To access the challenging chemical structure of …

We have achieved a bioinspired total synthesis of (+)‐euphorikanin A, which possesses an
intriguing and complex 5/6/7/3‐fused tetracyclic skeleton bearing a bridged [3.2. 1]‐γ …

A divergent strategy for the total syntheses of the indole terpenoid anominine (1) and its
natural congener tubingensin A (2) has been developed. The common intermediate 11 …

A concise synthetic approach to the hetisine C20-diterpenoid alkaloids is reported. The total
synthesis of (±)-nominine was accomplished in a 15-step sequence employing a dual …

A dual cycloaddition strategy for the synthesis of the hetisine alkaloids has been developed,
illustrated by a concise asymmetric total synthesis of (+)‐nominine (7). The approach relies …

The first total synthesis of anominine has been achieved, and the absolute configuration of
the product has been determined. The key features include the development of a new …

Divergent total syntheses of the enmein‐type natural products (−)‐enmein,(−)‐isodocarpin,
and (−)‐sculponin R have been achieved in a concise fashion. Key features of the strategy …

We detail the development of the first enantioselective synthetic route to euonyminol (1), the
most heavily oxidized member of the dihydro-β-agarofuran sesquiterpenes and the nucleus …