The rising interest on pathway complexity in supramolecular polymerization has prompted
the finding of novel monomer designs able to stabilize kinetically trapped species and …

Hydrogen‐bonded squaramide (SQ) supramolecular polymers exhibit uncommon
thermoreversible polymorph transitions between particle‐and fiber‐like nanostructures. SQs …

Despite a growing understanding of factors that drive monomer self-assembly to form
supramolecular polymers, the effects of aromaticity gain have been largely ignored. Herein …

Competing noncovalent interactions play a pivotal role in the folding and assembly of three-
dimensional structures, especially in flexible molecules. Calculations using density …

Herein, the impact of alkyl bridge length is unraveled on the self‐assembly of N‐annulated
perylenetetracarboxamides 1–4 that cooperatively form supramolecular polymers …

Intricately designed π‐conjugated molecules containing interactive groups can be used to
generate supramolecular polymers with outstanding structural and functional properties. To …

Supramolecular building blocks assembling into helical aggregates are ubiquitous in the
current literature, yet the role of solvents in these supramolecular polymerizations often …

Conspectus Supramolecular polymers, generated by connecting monomers through
noncovalent interactions, have received considerable attention over the past years, as they …

Monomers undergo supramolecular polymerizations via diverse pathways conferring
pathway complexity; deciphering the complexity has been an intriguing and fundamental …

We report the synthesis and self-assembly of a library of squaramide-based
bolaamphiphiles with variable hydrophobic and hydrophilic domain sizes, consisting of …