Half-sandwich organometallic Ru and Rh complexes of (N, N) donor compounds: Effect of ligand methylation on solution speciation and anticancer activity
A series of half-sandwich polypyridyl complexes was synthesized and compared focusing
on structural, cytotoxic and aqueous solution behaviour. The formula of the synthesized …
on structural, cytotoxic and aqueous solution behaviour. The formula of the synthesized …
Anticancer half-sandwich rhodium (III) complexes
Platinum-based anticancer drugs are most likely the most successful group of bioinorganic
compounds. Their apparent disadvantages have led to the development of anticancer …
compounds. Their apparent disadvantages have led to the development of anticancer …
Trinuclear Half‐Sandwich RuII, RhIII and IrIII Polyester Organometallic Complexes: Synthesis and in vitro Evaluation as Antitumor Agents
AR Burgoyne, BCE Makhubela… - European Journal of …, 2015 - Wiley Online Library
Schiff base ligands obtained from the condensation of 4‐aminophenylmethanol and either 2‐
pyridinecarboxaldehyde or salicylaldehyde were used to synthesise bidentate trimeric ester …
pyridinecarboxaldehyde or salicylaldehyde were used to synthesise bidentate trimeric ester …
Substitution‐Modulated Anticancer Activity of Half‐Sandwich Ruthenium (II) Complexes with Heterocyclic Ancillary Ligands
R Mitra, AG Samuelson - European Journal of Inorganic …, 2014 - Wiley Online Library
Ten new organometallic half‐sandwich ruthenium complexes with heterocyclic ligands have
been synthesized (H1–H10). The substituents on the ancillary heterocyclic ligands were …
been synthesized (H1–H10). The substituents on the ancillary heterocyclic ligands were …
Synthesis and evaluation of new polynuclear organometallic Ru (II), Rh (III) and Ir (III) pyridyl ester complexes as in vitro antiparasitic and antitumor agents
P Chellan, KM Land, A Shokar, A Au, SH An… - Dalton …, 2014 - pubs.rsc.org
New polynuclear organometallic Platinum Group Metal (PGM) complexes containing di-and
tripyridyl ester ligands have been synthesised and characterised using analytical and …
tripyridyl ester ligands have been synthesised and characterised using analytical and …
Anticancer Activity of Hydrogen‐Bond‐Stabilized Half‐Sandwich RuII Complexes with Heterocycles
R Mitra, S Das, SV Shinde, S Sinha… - … A European Journal, 2012 - Wiley Online Library
Neutral half‐sandwich organometallic ruthenium (II) complexes of the type [(η6‐cymene)
RuCl2 (L)](H1–H10), where L represents a heterocyclic ligand, have been synthesized and …
RuCl2 (L)](H1–H10), where L represents a heterocyclic ligand, have been synthesized and …
Organometallic Ru (II), Rh (III) and Re (I) complexes of sterane-based bidentate ligands: synthesis, solution speciation, interaction with biomolecules and anticancer …
T Pivarcsik, MA Kiss, U Rapuš, J Kljun… - Dalton …, 2024 - pubs.rsc.org
In this study, we present the synthesis, characterization and in vitro cytotoxicity of six
organometallic [Ru (II)(η6-p-cymene)(N, N) Cl] Cl,[Rh (III)(η5-C5Me5)(N, N) Cl] Cl and [Re …
organometallic [Ru (II)(η6-p-cymene)(N, N) Cl] Cl,[Rh (III)(η5-C5Me5)(N, N) Cl] Cl and [Re …
Tripodal Half‐Sandwich Rhodium and Iridium Complexes Containing Sulfonate and Pyridinyl Entities as Antitumor Agents
In light of the widely used platinum anticancer drugs showing high toxicity and poor
selectivity, the quest to develop new anticancer agents is increasing. This study investigated …
selectivity, the quest to develop new anticancer agents is increasing. This study investigated …
Tuning the Hydrolytic Properties of Half‐Sandwich‐Type Organometallic Cations in Aqueous Solution
L Bíró, AJ Godó, Z Bihari, E Garribba… - European Journal of …, 2013 - Wiley Online Library
Hydrolysis of half‐sandwich‐type platinum metal cations with the general formula [M (η6‐
arene)(H2O) 3] 2+{M= Ru, Os; η6‐arene= benzene, toluene, 1‐methyl‐4‐isopropylbenzene …
arene)(H2O) 3] 2+{M= Ru, Os; η6‐arene= benzene, toluene, 1‐methyl‐4‐isopropylbenzene …
Influence of the Arene Ligand, the Number and Type of Metal Centers, and the Leaving Group on the in Vitro Antitumor Activity of Polynuclear Organometallic …
MG Mendoza-Ferri, CG Hartinger, AA Nazarov… - …, 2009 - ACS Publications
Dinuclear ruthenium complexes were shown to exhibit strong antiproliferative properties in
human tumor cell lines. In order to extend the structure− activity relationships (SARs), a …
human tumor cell lines. In order to extend the structure− activity relationships (SARs), a …
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