The mechanism of the oxidative polymerization of aniline and the formation of supramolecular polyaniline structures

I Sapurina, J Stejskal - Polymer international, 2008 - Wiley Online Library
Polyaniline is one of the most important conducting and responsive polymers. A molecular
mechanism for the oxidation of aniline is proposed. This mechanism explains the specific …

Polyaniline nanostructures and the role of aniline oligomers in their formation

J Stejskal, I Sapurina, M Trchová - Progress in Polymer Science, 2010 - Elsevier
Polyaniline (PANI) is prepared by the oxidation of aniline. Depending on the acidity
conditions during the chemical oxidation, different types of products can be identified. The …

Oxidation of aniline: Polyaniline granules, nanotubes, and oligoaniline microspheres

J Stejskal, I Sapurina, M Trchová… - …, 2008 - ACS Publications
Aniline was oxidized with ammonium peroxydisulfate in solutions of strong acid (0.1 M
sulfuric acid), weak acid (0.4 M acetic acid), or alkali (0.2 M ammonium hydroxide). The …

Polyaniline nanotubes: conditions of formation

EN Konyushenko, J Stejskal, I Šeděnková… - Polymer …, 2006 - Wiley Online Library
The courses of aniline oxidation with ammonium peroxydisulfate in aqueous solutions of
strong (sulfuric) and in weak (acetic) acids, followed by temperature and acidity changes …

The genesis of polyaniline nanotubes

J Stejskal, I Sapurina, M Trchová, EN Konyushenko… - Polymer, 2006 - Elsevier
Aniline has been oxidized with ammonium peroxydisulfate in 0.4 M acetic acid. Protons are
produced in the course of oxidation and the pH decreases as the reaction proceeds. The …

Synthesis of polyaniline nanobelts

G Li, H Peng, Y Wang, Y Qin, Z Cui… - Macromolecular rapid …, 2004 - Wiley Online Library
Polyaniline nanobelts have been synthesized by a self‐assembly process using the
chemical oxidative polymerization of aniline in a surfactant gel. The morphologies of …

The intrinsic nanofibrillar morphology of polyaniline

J Huang, RB Kaner - Chemical communications, 2006 - pubs.rsc.org
Polyaniline nanofibers are shown to form spontaneously during the chemical oxidative
polymerization of aniline. The nanofibrillar morphology does not require any template or …

Evolution of polyaniline nanotubes: the oxidation of aniline in water

M Trchová, I Šeděnková… - The Journal of …, 2006 - ACS Publications
The course of aniline oxidation with ammonium peroxydisulfate in aqueous solutions has
been investigated. The reaction was terminated at various times and the intermediates …

Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications

G Ćirić-Marjanović - Synthetic metals, 2013 - Elsevier
Recent progress in synthesis, characterization, processing and application of polyaniline
(PANI), with the focus on the period 2010–2012, is reviewed. Special attention was paid to …

Oxidative polymerization of aniline: molecular synthesis of polyaniline and the formation of supramolecular structures

IY Sapurina, MA Shishov - New polymers for special applications, 2012 - books.google.com
The growing interest in nanostructured conducting polymers is caused by expanding area of
their practical application. Conducting polymers can be used in new electronic devices …