Measuring the mechanical properties of molecular conformers

SP Jarvis, S Taylor, JD Baran, NR Champness… - Nature …, 2015 - nature.com
Scanning probe-actuated single molecule manipulation has proven to be an exceptionally
powerful tool for the systematic atomic-scale interrogation of molecular adsorbates. To date …

Single-molecule tribology: force microscopy manipulation of a porphyrin derivative on a copper surface

R Pawlak, W Ouyang, AE Filippov… - ACS …, 2016 - ACS Publications
The low-temperature mechanical response of a single porphyrin molecule attached to the
apex of an atomic force microscope (AFM) tip during vertical and lateral manipulations is …

Directed rotations of single porphyrin molecules controlled by localized force spectroscopy

R Pawlak, S Fremy, S Kawai, T Glatzel, H Fang… - ACS …, 2012 - ACS Publications
Directed molecular repositioning is a key step toward the build up of molecular machines. To
artificially generate and control the motion of molecules on a surface, excitations by light …

Physisorption controls the conformation and density of states of an adsorbed porphyrin

SP Jarvis, S Taylor, JD Baran… - The Journal of …, 2015 - ACS Publications
Conformational changes caused by adsorption can dramatically affect a molecule's
properties. Despite extensive study, however, the exact mechanisms underpinning …

Forces during the controlled displacement of organic molecules

G Langewisch, J Falter, H Fuchs, A Schirmeisen - Physical Review Letters, 2013 - APS
In the ongoing effort to miniaturize the functional elements in electronic devices, molecular
dimensions are currently approached. Scanning probe microscopy has demonstrated …

Quantifying the atomic-level mechanics of single long physisorbed molecular chains

S Kawai, M Koch, E Gnecco… - Proceedings of the …, 2014 - National Acad Sciences
Individual in situ polymerized fluorene chains 10–100 nm long linked by C–C bonds are
pulled vertically from an Au (111) substrate by the tip of a low-temperature atomic force …

Angle-dependent atomic force microscopy single-chain pulling of adsorbed macromolecules from planar surfaces unveils the signature of an adsorption–desorption …

L Grebíková, SG Whittington… - Journal of the American …, 2018 - ACS Publications
The adsorption–desorption behavior of polymer chains is at the heart of macromolecular
surface science and technology. With the current developments in atomic force microscopy …

[HTML][HTML] The role of surface corrugation and tip oscillation in single-molecule manipulation with a non-contact atomic force microscope

C Wagner, N Fournier, FS Tautz… - Beilstein journal of …, 2014 - beilstein-journals.org
Scanning probe microscopy (SPM) plays an important role in the investigation of molecular
adsorption. The possibility to probe the molecule–surface interaction while tuning its …

Direct identification and determination of conformational response in adsorbed individual nonplanar molecular species using noncontact atomic force microscopy

F Albrecht, F Bischoff, W Auwärter, JV Barth… - Nano Letters, 2016 - ACS Publications
In recent years atomic force microscopy (AFM) at highest resolution was widely applied to
mostly planar molecules, while its application toward exploring species with structural …

Dynamic force spectroscopy of molecular adhesion bonds

B Heymann, H Grubmüller - Physical Review Letters, 2000 - APS
Recent advances in atomic force microscopy, biomembrane force probe experiments, and
optical tweezers allow one to measure the response of single molecules to mechanical …