In contrast to the well‐established [3+ 2] cycloaddition reactions, the catalytic
enantioselective [3+ n](n≥ 3) cycloaddition reaction of activated isocyanides for the …

An unprecedented copper (II)‐catalyzed enantioselective 1, 3‐dipolar [3+ 4] cycloaddition of
azomethine imines with in situ formed azoalkenes has been realized. This strategy provides …

A silver (I) and base-mediated [3+ 3]-cycloaddition reaction of in situ generated C, N-cyclic
azomethine imines with in situ formed aza-oxyallyl cations is reported. This one-pot …

Aminoallyl cations are versatile 1, 3‐dipoles that could potentially be used for diverse (3+ n)
cycloaddition reactions. Despite some preliminary studies, the asymmetric catalytic …

The first enantioselective formal [3+ 2] cycloaddition of aurone analogues with
isocyanoacetates was developed via chiral Ag-complex catalysis. A variety of optically …

A highly selective and practical asymmetric Ag (I) catalyst system has been developed for
the [3+ 2] cycloaddition reactions between isocyanoacetates and cyclopentenediones. The …

Heterocyclic compounds containing a chiral pyrrolidine motif commonly appear in natural
alkaloids and pharmaceutically active substances, and serve as building blocks commonly …

Silver‐standard selectivity! The first highly enantioselective formal [3+ 2] cycloaddition
reaction of isocyanoesters with 2‐oxobutenoate esters catalyzed by a chiral silver complex …

α-Acidic isocyanides are versatile reagents in organic synthesis, especially for the synthesis
of five-membered heterocycles via [3+ 2]-cycloaddition reactions with activated multiple …

Presented herein is a new complexity‐generating method in which both functionalities of α‐
imino esters undergo stereoselective cyclization with isocyanoacetates to produce directly …