We present a new, unified approach for the transformation of benzylic and allylic alcohols,
aldehydes, and ketones into boronic esters under electroreductive conditions. Key to our …

Direct conversion of aldehydes and ketones into alkylboronic esters via deoxygenative
borylation represents an unknown yet highly desirable transformation. Herein, we present a …

Herein, a fast, scalable, and transition-metal-free borylation of alkyl halides (X= I, Br, Cl)
enabled by electroreduction is reported. This process provides an efficient and practical …

An efficient method for the metal‐free deaminative borylation of alkylamines, using bis
(catecholato) diboron as the boron source, to directly synthesize various alkyl potassium …

Organoboron reagents are important synthetic intermediates and have wide applications in
synthetic organic chemistry. The selective borylation strategies that are currently in use …

A deoxygenative gem-diborylation and gem-silylborylation of aldehydes and ketones is
described. The key for the success of this transformation is the base-promoted C–O bond …

Carboxylic acids are readily available, structurally diverse and shelf-stable; therefore,
converting them to the isoelectronic boronic acids, which play pivotal roles in different …

Polyborylated organic compounds have been emerging as versatile building blocks in
chemical synthesis. Here we report a selective cobalt-catalyzed deoxygenative 1, 1, 3 …

A catalyst-free oxyboration reaction of alkynes is developed. The resulting borylated
isocoumarins and 2-pyrones are isolated as boronic acids, pinacolboronate esters, or …

We report the regiospecific, rhodium-catalyzed borylation of saturated terminal C− H bonds
in molecules with existing functionality. Moderate to good yields were obtained with the …